Hi all.
Chimneys come in many sizes and styles. From the OLD brick styles, to the newer multi layered metal and insulation types.
The key for best performance of a chimney is to keep the gasses inside as hot as possible, to maximize available draft, and to keep deposits from condensing (creosote) on the chimney itself. But then you need to keep the outside of the chimney cool enough so you don't burn your house down.
Many designs have come and gone through the years.
Starting with the old tried and true Brick. They do work but are hard to get warm to provide a good draft, plus the creosote condensation is a major issue due to the inside being quite cool for a LONG time when first starting a fire.
Single layer metal tube gets hot FAST so buildup is minimal, but of course the outside of the chimney is also just as hot and can easily start near by combustables on fire.
One cure to this was to make a coaxial chimney, like this,

Where the hot inner liner can get nice and hot to make good draft AND lessen creosote buildups due to cold temps. the outer layer is much cooler because of the air gap helps insulate it from the hot inner tube. This works pretty well, so the idea was extended to a triple wall system like this,

and it indeed did work even better. But the chimneys started getting really large now in diamaters. like that 8" id chimney, now has a 12" od!
So someone to get the same amount of Hot inside / cool outside came up with a two layer again ,but instead of an air gap insulation, they stuffed in the gap a fireproof type of insulation. so it was built like this now.

And it works great.
This all leads up to the thought,
To maximize the keep hot inside as hot as possible to maximize draft and minimize creosote buildup. Yet keep the outside as cool as possible to not burn down building,
combine the two ideas!?
Take that triple wall chimney,

And the inner airgap fill with a fireproof insulation. Just like the two layered insulated chimney. then there is the added extra air gap too.
I was thinking of doing this, and started first oldschool like Vermiculite, or perlite.
And when searching for that stuff have found newer high tech materials just like them where I could pour them into that inner gap and with a vibrator make sure they fill the inner void fully.
Thoughts anyone?