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Deodorizing and Compacting Waste from Abaca Pulping

03/03/2014 11:33 PM

A pulping plant here in northern Mindanao makes trade pulp from abaca (Musa textilis - also known as Manila hemp). The trade pulp is exported to Europe, where it is made into currency paper primarily. The process, which is treated as a trade secret but which I think is a variation on the kraft or sulphate process, produces a large volume of waste which, quite frankly, stinks. Because of the odor primarily, they have to pay to have it taken off the plant property and landfilled somewhere under conditions which won't stink up homes and farms. This is expensive. The plant is profitable only because of the high added value of the pulp, due to its end use, and because of relatively low labor costs compared to Europe.

I would like to find a solution to the problem, not only for the immediate reward but because a solution would make the process as a whole cheaper, which would open it to other fiber sources and other end-uses and thus increase exports in this field.

The sample I just received is semi-solid, with the texture (felt through the sealed plastic bag which I haven't dared open because I can smell the stuff THROUGH it) of fresh horse manure. The odor, while fecal in nature, is unfortunately much more objectionable than that of a stable.

The first order of business, then, is to suppress the odor. This would open up the possibility of further reducing the moisture content, which might make it practical to burn the stuff. The literature that I've dug up so far talks about the use of ozone and/or chlorine dioxide for deodorizing. I think that chlorine dioxide should be relatively easy to generate from hydrochloric acid, which is available here at reasonable cost, but I don't know what effect this would have on combustibility of eventual solid residue, how much would be needed and how it would be applied.

I notice that most Kraft mills burn their residue to provide heat for the plant, but I assume this is not done here because of the low lignin content of abaca and the absence of resins, and the fact that those are the primary combustible organic components of the usual kraft waste from wood.

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#1

Re: Deodorizing and Compacting Waste from Abaca Pulping

03/04/2014 7:49 AM

Is there some chemical remains left in this waist product that prevents it from being used for compost?

I grew up down wind of a sugar beet processing plant, and they had rotting piles of waist pulp, which also was an unwelcome smell. The beet growers would joke this smells like money. It took years for them to figure out to haul it back out to the fields and used it as compost.

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#3
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Re: Deodorizing and Compacting Waste from Abaca Pulping

03/05/2014 7:34 AM

Good question. I don't have a chemical analysis. I'm assuming that any alkali residue has been neutralized, and the fecal odor tells me there are mercaptans present, but I know nothing more than that. I will try composting the stuff. Maybe that's what those taking on the waste are doing with it...

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#2

Re: Deodorizing and Compacting Waste from Abaca Pulping

03/04/2014 6:37 PM

There's more in this paper than I could ever understand. Hope this helps.

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#4
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Re: Deodorizing and Compacting Waste from Abaca Pulping

03/05/2014 7:40 AM

It's a good paper, but it's about the useful product of abaca pulping...not the waste. Love the former...but it's the latter I am trying to deal with.

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#5
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Re: Deodorizing and Compacting Waste from Abaca Pulping

03/05/2014 8:43 AM

Some of those compounds are awfully smelly, I assumed that the waste product can't be totally free from them so there would be some carryover. Have you done a spectrographic analysis of the waste so you can spot the compounds of interest? Sometimes a digester or fermenter can change those compounds into something less smelly or more useful, again this is way out of my field, I nearly flunked organic chemistry.

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#6
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Re: Deodorizing and Compacting Waste from Abaca Pulping

03/05/2014 10:02 AM

I'm afraid I wouldn't know where to find the apparatus to perform a spectrographic analysis, or what to do with it once found, or how to interpret the results. This is an ad hoc effort. My formal training - such as it is - is in mechanical, not chemical engineering.

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Re: Deodorizing and Compacting Waste from Abaca Pulping

03/05/2014 10:55 AM

Ok, so you want something mechanical, try drying it in the sun on some large black sheeting then seeing if the material burns. Don't forget to weigh it before and after to get an idea what the moisture content is.

I would also try composting, fermenting, and digesting it. Composting is easy but not predictable, but there's plenty to Google on for the other two, you might even get methane as a useable by-product.

There are many dairy farms that feed cow pooh into a digester and get methane and fertilizer as output products. Some people take it a step further and turn biomass into ethanol or biodiesel.

The Philippines seems to have many organizations devoted to using the existing biomass, maybe you can contact them. Just do your own research to make sure that there still something useful left in all that waste, you don't want to find out later that it's all ash and no fuel.

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#8
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Re: Deodorizing and Compacting Waste from Abaca Pulping

03/07/2014 4:01 AM

Drying it is something I very much want to do - it's the first essential step in really learning what's in there. Unfortunately, the stuff stinks so badly that my neighbors will be in full revolt if I don't solve the stink problem first.

One of the bizarre schemes I'm trying to work on right now is using ozone to deodorize the air leaving a solar dryer that would be a slightly more sophisticated version of the black polyethylene sheet that you suggest. There is late nineteenth century, early twentieth work that suggests that a very small amount of ozone cancels odor from sewage treatment ponds, and that is very much the nature of this stuff. I need to gin up an improvised ozone generator to test that.

One thing I do know from the source is that this stuff is biologically active, so direct composting is well worth trying as well, as suggested earlier. I've taken one crude step toward that by burying a small amount of the stuff (the excess of my "sample") in the garden with wood ash and some kitchen waste. The main purpose was to hide the odor, but I will definitely dig it up again later to see how it has evolved.

Anaerobic digestion in slurry form does need to be tried, too, though that takes a bit more apparatus.

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