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Turning Carbon Dioxide Into Bioplastics

Posted August 02, 2011 7:58 AM

From Discover Technology:

George Washington University chemist Stuart Licht thinks he can slash atmospheric carbon dioxide to preindustrial levels in a decade, harnessing the sun's power to make useful products at the same time. His bold claim is based on a technology called STEP (Solar Thermal Electrochemical Production), which taps solar energy to break down CO2 and other compounds into their constituent elements. These elements would ultimately be recombined to make plastics and fuel.

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#1

Re: Turning Carbon Dioxide Into Bioplastics

08/03/2011 8:40 AM

Hmmm, interesting. I don't know if it will be cost competitive or even scalable. He will probably need some luck with the sand blasting of the PVs. He is going to create quite a bit of ozone. At ground level in a completely barren desert, I am not sure what affect it will have on the environment. If placed in the areas where vegetation grows or upwind of those areas, the ozone is going to do a lot of damage.

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#2

Re: Turning Carbon Dioxide Into Bioplastics

08/03/2011 12:12 PM

If it is easy, and cheap, then it should be possible to make a prototype. When I see a hundred charcoal briquettes a minute being spit out of this machine, I'll take it seriously. (That is...I will supply money.) Until that happens, it sounds like a snipe hunt.

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#3
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Re: Turning Carbon Dioxide Into Bioplastics

08/03/2011 12:59 PM

There is a chicken-and-egg problem here. Until serious engineers see a commercial device, it does not deserve their attention, but until serious engineers take a close look at it, this idea will never become a commercial device. It is presumed guilty of being a snipe hunt, without examination. And even a prototype will be dismissed as not scalable to deal with utility-scale emissions.

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#4
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Re: Turning Carbon Dioxide Into Bioplastics

08/03/2011 5:05 PM

Let's see... The proposal calls for a set of these converters with the footprint 4% of the Sahara Desert.

So, one hundred forty five thousand square miles. 145,000 Mi2. Possibly a rectangle 300 miles by 480 miles. The entire state of Montana.

A ten percent scale prototype would be the size of Rhode Island, Delaware, New Jersey and Connecticut combined. A one percent scale prototype would be about the size of Rhode Island.

That is not an inconsiderable chicken-and-egg.

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#5
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Re: Turning Carbon Dioxide Into Bioplastics

08/03/2011 6:02 PM

I have a wood lot out back of my place. It converts Carbon Dioxide into burnable wood, with a remarkable amount of useful structural wood as a by product. We already have a bio-plastic...its called timber. Such a gaget would have to exceed this production. A swamp of only a few meters square can produce a huge amount of biomass, which again, can be turned into fuel, or an oil substitute, or can be buried to be used to create oil for future gerations. And ducks can nest in a well managed swamp.

That being said, I didn't suggest or ask for a prototype the size of Delaware, just one big enough to spit out charcoal briquetes faster than I could get them from a wood lot before I would bother to look at it. If it was as easy and as cheap as the OP suggests, that should be easy to do. And I still won't be interested in putting money into it until it could be shown to be "scaleable", "saleable" and commercially viable. At which time, you will have to fight off BIG COAL's patent lawyers. If you want chase down snipes, be my guest...there are plenty out there. Some of them even exist.

(water injected engines comes to mind, though hydrogen fuel cells and wave generators come in second and third.)

At least it is not an over unity device.

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#6
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Re: Turning Carbon Dioxide Into Bioplastics

08/04/2011 6:31 PM

Yusef, I may not been clear in my comment.

It's true you didn't suggest or ask for a prototype the size of Delaware. The point of my comment really is: Why bother to prototype at all? This thing is not constructable at a 1% scale, let alone full size. What construction project on the face of the earth even begins to approach the size of the state of Rhode Island? I cannot think of one.

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Re: Turning Carbon Dioxide Into Bioplastics

08/04/2011 9:46 PM

No, you were perfectly clear sir. I agree with you whole heartedly and without reservation.

The whole issue of advanced technology being driven by "green" dollars is what makes it a snipe hunt. This idea does not exist outside of the lab, yet it is suggested that it could be the answer to global warming. As far as I could tell, you don't NEED an array the size of Delaware, just one that big if the goal was to reduce greenhouse gasses by ten percent per year. If you have more modest goals, well, it will take longer. And you are right, nobody will ever actually BUILD such a device!

No, this is not a gaget, or a process, or even a working design, it is an idea. An idea is the cheapest currency in the modern interweb age. This idea might well have some legs as a production facility in say, a desert area which otherwise has little or no industry,...but as the answer to green house gasses....come on. Pull the other one...its got balls on it! The OP suggested that he could do that with enough photocells. ten percent of the surface area of the sahara was mentioned! Lordy, with that many photocells, we won't be burning any coal for electricity will we? Oh, except for the tremendous amount of energy which would be needed to make the photocells! Nahhhh....it doesn't pass the smell test. It reeks in fact, BECAUSE it is labeled as the answer to global greenhouse gasses, not as an answer to a lack of bioplastics or a source of jobs, or whatever.

This may be an idea. Maybe even a good idea. The journey of a thousand miles does not start with a single step, but rather with the idea that perhaps we can start a trip. How do you determine if an idea might be good? Well, you make a prototype. If it works, then you see if it can be scaleable. See if you can use the byproducts, if any to help pay for itself. I suggested charcoal briquettes....I suppose bioplastics are useful too. Rayon is a bio plastic. As is Cellophane. I think they take a few other chemicals to get them to work. At least you can "sell" charcoal briquettes. Every ton of charcoal you burn is a ton you don't need to dig out of the ground, which will reduce the greenhouse gasses being ADDED to the atmosphere. Every step counts...

Anyway, I have become unfocused, and am starting to rant. I guess it is because I tried to get a few hundred local kids organized to plant trees last week, and our funding collapsed at the last moment. That was MY modest way to reduce greenhouse gasses. Just think....how many trees would you have to plant to get three and a half cubic miles of timber? And all it takes to the will to get out and plant trees. Where is my "green" funding! Grrrr. Grrrr.

(And yeah...its a LOT of trees! But three and a half cubic miles is how many you would have to plant, then harvest to equal the oil we are dragging out of the ground every year!. A single step, or tree and all that! Besides...I like trees. Better than I like solar arrays. )

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#8

Re: Turning Carbon Dioxide Into Bioplastics

08/17/2011 4:37 PM

Just across the bay from here. They have secured some funds to go the extra mile and seem to be very optimistic about it. They claim it as a world first, go figure.

http://www.jcu.edu.au/blogs/atjcu/entry/innovative_algae_to_fuel_project

Good funding, Ky.

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Re: Turning Carbon Dioxide Into Bioplastics

08/18/2011 10:47 AM

I wish I wasn't such a suspicious auld phart, but so many of these projects seem to exist only to get funding, and when the funding dries up, the power plants vanish. It is like SO NOT a world's first!

The University here in Peterboro was digesting water hyacinth which was dragged out of the trent canal over thirty years ago. They are still doing that. (that link was to ASTRA, an Indian development site which is doing great things!) Usually of course, it is mixed with cow manure to aid digestion, and it seems to be a way to get rid of garbage! (That has to be good!) There do seem to be some problems, but of course the basic idea is sound.

I wish them luck. I remember a lecture I attended which suggested that the entire Don River (so polluted that it once caught fire!) through Toronto could be made crystal clear in only a hundred meters by making beds of water hyacinth for it to flow through. But the resultant biomass would not be good cattle feed because the plant takes all the heavy metals and other contaminants out of the water.

It has occured to me since that lecture that if that can be done, then why is it NOT being done? That question MUST be answered to everybody's satisfaction before wasting time and money by either re-inventing the wheel or splashy new tech with limited potential.

They are not difficult questions. I only fear that the political will is missing....the technology is there now.

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#10
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Re: Turning Carbon Dioxide Into Bioplastics

08/18/2011 3:55 PM

They had a local TV special and sold it as "the world first". Unless they are keeping the kernel secret nothing is new.

I could hop on a ferry, watching whales on the way and ask them? But without a chequebook in tow they are not going to open their books.

There is a fine line between scientific fraud and exaggerating to investors. I think, in this specific case, the journos have a lot to answer for, no surprise there though.

Nothing comes from everything, Ky.

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