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What Is a Spectrophotometer and What Does It Do?

Posted June 30, 2013 12:00 AM by Daniel Harris
Pathfinder Tags: spectrophotometer

Several years ago I was monkeying around in the garage when I stumbled upon a handful of old paint cans. Being both the inquisitive type, and one not inclined to let any product go to waste, I quickly opened them up to determine their usefulness. It seemed like the paint was still good, a few hard shakes and stirs and we were good to go.

But the colors were varied and each was frankly, a little boring. So I did what any creative person would do -- I began mixing and matching. After an hour or so of mad-scientist sorcery, my masterpiece was complete. I had invented a new color (or so I thought), a paint that resembled Grey Poupon, a spicy yellow mustard with a hint of brown. I later learned that my "invention" was similar to an existing "color" known as Gamboge.

I really liked this color, and decided to paint the trim of my garage with this lovely mustard tinge... but I ran out of my new concoction before I could apply it evenly throughout the garage.

I was in big trouble, but I didn't realize it.

I thought it would be as simple as taking a sample of my invention down to the paint store and find a reasonable match and go from there. But it turns out my creation was far too, well creative, to match anything existing down at the local hardware store.

I even tried a different yellow/brown tint, but it was clear that it wasn't the same. I wanted Grey Poupon, and I was getting French's;

So I began learning about colors and what it is that distinguishes them. Turns out that color can be described by how "pure" or "unsaturated" it is, along with a corresponding "value" or "lightness". Each shade can be categorized in many ways, hundreds of ways, actually. In actuality, color is a combination of "wavelengths" that include: x-rays, ultraviolet, visible light, infrared, microwaves, and radiowaves.

My head hurt. There was a lot more to colors and color matching than I had realized.

And I was demoralized. How would I ever be able to find the exact match to the color I had invented?

Then I learned about a spectrophotometer, a high-tech gadget that would solve all my problems!

A spectrophotometer is used for matching paint colors precisely. I'd explain to you exactly how the spectrophotometer works, but then you'd also have a headache and frankly, I don't fully understand the particulars, either. All I know is the machine has proven effective at matching my Grey Poupon color to an exact match! The entire process of using the spectrophotometer was simple; despite its sci-fi abilities, it is actually a very user friendly piece of machinery.

With the use of the spectrophotometer, or a color spectrometer as they are sometimes referred (and they are slightly different though similar tools), you can get a match up to 95% accurate, sometimes even more precise.

With the help of a spectrophotometer, I had all the blank canvas in my garage adorned in the wonderful brown mustard color that I adore, that color which I invented and have since submitted to Crayola for inclusion in their next coloring set.

Editor's Note: Daniel Harris is a freelance writer working with BYK Additives and Instruments who specializes in offering manufacturers ways to maintain quality control across multiple plants

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#1

Re: What Is a Spectrophotometer and What Does It Do?

06/30/2013 12:15 AM

Spectrophotometers are fine.

But they will never convince a determined woman that that discoloration in the hallway is a shadow.

Never mind that it wasn't there all the time.

God love 'em!

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#2
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Re: What Is a Spectrophotometer and What Does It Do?

06/30/2013 12:20 PM

That reminds me of some people I met once that are good friends of my aunt and uncle.

We went over to see their new house as they were finishing building it.

The wife was going on and on about the different colors she chose for each room and whatnot. We finally got to the main living room on the lower level and she was talking about the how the subtle difference between the desert sand color on the walls and the off tan whatever on the ceiling make for such a nice but subtle contrast. Personally my uncle and I could not tell the difference.

Anyway we followed the husband out to the garage and he commented on how many weeks it took his wife to pick out the colors. He said she spent a week alone on the two stupid living room colors however the week before when he went to paint the room he couldn't remember which she wanted on what and it was late so he opened the two colors mixed them together then sprayed the ceiling and walls with the mix all in one shot then dumped the remainder into two cans, one labeled touchup for each, and called it good.

He said that at least 30 women have been through that house this week and everyone of them can see the subtle difference between the two colors. He however guarantees that they are exactly the same being he mixed and sprayed them himself!

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#3
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Re: What Is a Spectrophotometer and What Does It Do?

06/30/2013 4:01 PM

Tell him, for me, that he better have that paint color matched and on hand for touch-ups.

Some things are better left alone. If women think they can discern these color subtleties and it keeps us from re-painting, I say let them.

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#5
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Re: What Is a Spectrophotometer and What Does It Do?

06/30/2013 11:35 PM

Well thats what he did in the end. Two separate cans each labeled for the different paint color but inside they are both the exact same paint mix he blended together from the originals himself.

Personally between you and me being I have been married two years now I too have a few little secrets like this already that in a sick sort of way give me satisfaction justification to feel that my wife is nuts as well.

They make her happy and I get to grin for my own reasons as well.

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#6
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Re: What Is a Spectrophotometer and What Does It Do?

06/30/2013 11:40 PM

Two years?

You aren't even really MARRIED yet if it's only been two years.

I've got over 20 years with two different women. Not at the same time, either.

I still don't get it.

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#19
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Re: What Is a Spectrophotometer and What Does It Do?

07/05/2013 9:22 AM

Heck... 32 years here with the same one and some things are still a mystery. And you know what... I hope it stays that way. Keeps things interesting if you ask me.

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#8
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Re: What Is a Spectrophotometer and What Does It Do?

07/01/2013 7:25 AM

That's a good story!

The actual reflected color is a combination of the paint color and the illumination color, which is why colors sometimes look different under fluorescent lighting. I can imagine that the light illuminating the ceiling might be a slightly different color from that hitting the walls since the ceiling is facing the floor. The eye does a good but not perfect job of cancelling out the effect of illumination. It might be interesting to take a photograph and see how the colors compare.

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#20
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Re: What Is a Spectrophotometer and What Does It Do?

07/21/2013 11:48 PM

Rixter: "The actual reflected color is a combination of the paint color and the illumination color"

You got it right. Reflected color is a processed color and its intensity down and once again when reflected by another surface causes a shadow or even difference in color as reflection is not in same proportion for all colors or Photon Energies (which is what we call color E = hv) and sometime also expressed in wavelength in nm. Color is defined for a white light source of all energies / wavelengths (nearly) uniformly present.

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#17
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Re: What Is a Spectrophotometer and What Does It Do?

07/02/2013 9:59 AM

Well, since the stuff in the can is still wet it wouldn't look like the same shade, so how can they be so sure?

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#18
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Re: What Is a Spectrophotometer and What Does It Do?

07/02/2013 10:02 AM

Lol, yes. But if you have a spectrophotometer you can make a stronger case. Not that it will help the marriage...

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#4

Re: What Is a Spectrophotometer and What Does It Do?

06/30/2013 11:22 PM

From my experience in the medical device industry, a spectrophotometer can only tell the denstity of, in this case, paint - send light through a clear medium then send the light through the sample (paint) then calculate the difference. This is done with human blood to figure the hemoglobin (iron) in the patient sample.

Chemistry systems can look at different wavelengths, again the light must shine through the sample.

I fear with the paint, it may be too dense for the light to shine through. I know of several local paint shops that claim "we will match your paint color". Maybe if your purchased paint was not a good match, you might want to find another paint professional to match your mustard!

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#7
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Re: What Is a Spectrophotometer and What Does It Do?

07/01/2013 2:47 AM

Hemoglobin is determined by transmission spectroscopy, whereas, paint samples are measured by reflectance spectroscopy. In reflectance spectroscopy, the opaque sample is illuminated by a white light and the reflected light is analyzed for its spectral content using a pure white sample as a blank (baseline).

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#9

Re: What Is a Spectrophotometer and What Does It Do?

07/01/2013 8:44 AM

Interesting article.

Spectrophotometers have lots of other uses. As it turns out, aviation people are rather particular about cockpit lighting. They like to have the EXACT shade of red, green, blue, pink, yellow, orange, white, (even black) on all their cockpit displays. It can be a tough job to get them to match, especially when a particular LCD goes obsolete, and you've got to try to match the lighting using multiple sources of LCDs and LEDs.

Oh, and compatibility with night vision goggles, too? So no real deep reds, only orangy-reds. Right, got it.

Yeah, spectrophotometers (aka, spectroradiometers) can be pretty useful.

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#16
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Re: What Is a Spectrophotometer and What Does It Do?

07/02/2013 9:53 AM

Not just that. I've since learned that the same technology, albeit with a much wider sample of wavelengths, is used to determine the chemical composition of stars. Kind of makes me wish I'd studied physics.

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#10

Re: What Is a Spectrophotometer and What Does It Do?

07/01/2013 9:42 AM

No one can see colours just the reflection, now just what is causing the light that allows a reflection? Direct sunlight, indirect sunlight, reflection off of close by objects. Mix all you want but be aware of the variations caused by the lighting source or sources.

With regards to the lady in your life when building our last house I was using a 4 ft. level to hang the cupboards and my dear wife stood back and claimed that the level was incorrect. We never did settle that incident to her satisfaction.

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Re: What Is a Spectrophotometer and What Does It Do?

07/01/2013 11:23 AM

If your house is anything like my 1973 vintage track development slapped together house, there is a saying in the neighborhood that nothing is flat, level, square, plumb or straight.

Therefore, even if your cupboard is hanging such that it is perfectly level, nothing else is level and therefore "looks" wrong??

Of course those living in much older homes often have floors that shed water quite nicely. We used to be able race matchbox cars on the kitchen floor where I grew up.

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Re: What Is a Spectrophotometer and What Does It Do?

07/01/2013 12:46 PM

The 150 year old farmhouse I was raised in was similar, Dining room to living room had a slope that toy cars would coast down. Dad jacked the house as much as possible to straighten it then installed hydronic heating on the floor and leveled as much as possible with concrete. Nice job and warm to play on.

Every time I walk into a factory built house the squareness is evident compared to a normal built on site structure. They may be quite close but to my eye the exactness of the factory homes stands out.

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Re: What Is a Spectrophotometer and What Does It Do?

07/01/2013 12:55 PM

We have been through similar issues with dad when it came to replacing old walls and windows in some of our old farm buildings.

He likes to make everything perfectly straight and level which is fine except when you do it in a crooked building. The new part just never looks right or like it belongs there afterwards.

Then on the other hand I have friends of mine who added a boiler room to their shop some years ago and built it crooked mostly because they were in too big of hurry to ever measure anything.

Adding a crooked addition to a crooked building should fit just fine of course unless you get your crooked directions wrong then it just makes the new part look even worse.

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#14
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Re: What Is a Spectrophotometer and What Does It Do?

07/01/2013 6:17 PM

THIS. How many pictures have I checked in the upstairs office of our ~90 year old home to find that they are on-bubble, and the ceiling or nearest corner is not.

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Re: What Is a Spectrophotometer and What Does It Do?

07/01/2013 6:23 PM

Double sticky back foam tape?

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