Previous in Forum: crystal structures   Next in Forum: Two-Phase Heat Exchanger
Close
Close
Close
10 comments
Rate Comments: Nested
Participant

Join Date: Feb 2008
Posts: 3

Can You Cook Plastic Too Long?

02/10/2008 6:16 PM

I am doing some reseach on Roto molding plastic. I see they "Cook" or heat the plastic powder for long periods of time. Is this necessary? If the plastic melts at 275 F do I have to heat it to 350F for 10 minutes, or would 1-2 min be enough? How hot is hot enough?

Register to Reply
Interested in this topic? By joining CR4 you can "subscribe" to
this discussion and receive notification when new comments are added.

Good Answers:

These comments received enough positive votes to make them "good answers".

"Almost" Good Answers:

Check out these comments that don't yet have enough votes to be "official" good answers and, if you agree with them, vote them!
Guru
United Kingdom - Member - Not a New Member Hobbies - Musician - New Member Hobbies - Fishing - New Member

Join Date: May 2006
Location: Reading, Berkshire, UK. Going under cover.
Posts: 9684
Good Answers: 468
#1

Re: Can you "Cook" Plastic too long?

02/10/2008 7:20 PM

You have to obey the manufacturer's instructions - unless you want to take the risk, yourself, of the moulded pieces falling apart.

Personally, I haven't go a clue. It may work, but there'll be no come-back if they all collapse in a couple of years - it'll be on your head.

__________________
"Love justice, you who rule the world" - Dante Alighieri
Register to Reply Score 1 for Off Topic
Guru
New Zealand - Member - Interested in everything- see my Profile please APIX Pilot Plant Design Project - Member - Member Engineering Fields - Electrical Engineering - Member Engineering Fields - Power Engineering - Member Engineering Fields - Civil Engineering - Member Hobbies - Musician - Autoharp and Harmonica Hobbies - Hunting - Member Hobbies - Fishing - Member

Join Date: Nov 2007
Location: Christchurch, (The Garden City), South Island, New Zealand
Posts: 4395
Good Answers: 230
#2

Re: Can you "Cook" Plastic too long?

02/10/2008 9:34 PM

Hello OleTechGuy

As JohnDG states above, best to use the combination of Roto-oven and plastic pellet/powder manufacturer's advice.

Generally Roto-ovens use Thermoplastics such as Polyethylene, Polystyrene, and these don't have a problem when exposed for a long period to slightly above melting point.

Often too, the objects are thick and require longer heating to ensure correct melting, and so the cross-linking can properly take place on the cooling cycle.

As JohnDG said, you don't want a product which parts fall out of, later, do you.

Thermosetting plastics are different, of course, because they require a one-shot heating/cooling process.

Kind Regards....

__________________
"The number of inventions increases faster than the need for them at the time" - SparkY
Register to Reply Score 1 for Good Answer
2
Commentator

Join Date: Feb 2008
Location: Somewhere south of Canada
Posts: 68
Good Answers: 1
#3

Re: Can you "Cook" Plastic too long?

02/11/2008 11:45 AM

Generally lower temp "cooking" is to desiccate the material prior to molding, and water content directly affects your UTS, so yes this is very important. As for heating the plastic above the liquidus or glass transition temp generally it depends on how much material your are melting and the desired viscosity for molding. If your material is cheap enough you can do the optimization yourself, if its on the spendy side call the manufacturer.

__________________
All this worldly wisdom was once the unamiable heresy of some wise man. -Thoreau
Register to Reply Good Answer (Score 2)
3
Active Contributor

Join Date: Feb 2008
Posts: 11
Good Answers: 2
#4
In reply to #3

Re: Can you "Cook" Plastic too long?

02/11/2008 1:07 PM

All good general comments above BUT the answer is YES YOU CAN OVERCOOK any plastic. At lower temperature, it takes longer time than at higher temperatures (liquidous). Below Tg the temperature effect is simply ageing. Above liquidous, there is the phase transformation, which changes molecular orientation and density upon cooling (i.e. HDPE may be of lower density). Much above liquidous, we are talking major degradation because the energy is enough to break the bonds. Thus, the MW distribution will develop a long tail to the left (lower Molecular Weights) and a huge loss in properties. Rotomolding DOES not require melting, just sticking of the powder particals together, slowly layer by layer starting on the outside. I hope this helps...drago-the-composites-guy

Register to Reply Good Answer (Score 3)
Participant

Join Date: Feb 2008
Posts: 3
#5
In reply to #4

Re: Can you "Cook" Plastic too long?

02/11/2008 5:18 PM

Thanks for the help. I have started working in this business and was looking for more info. When I asked the same questions of my co workers they had no answers other than "thats what we have been doing for 20 years". I'm more of an analyitical type so I like to know whys and whats happening.

I did some testing where I actually measured the temp in the moulds. The plastics mfg says that the melting point is 260 F. During the normal cycle we reached as high as 380 F. I then did a part where I went to 260 F and shut off the oven. The temp rose for another few min before starting to level out at 280 F, then dropped. When it again cooled to 260 F I started the cooling cycle. I removed the part when the inside temp was 160 F. The part looked the same, except that the inside (which you can't normally see) was not as glossy as the longer hotter one. The plastic had melted and fused just fine, and the outside finish was to the eye just the same. The part also was a little bit thicker. Without waiting 10 years, I'd like to know if the cooler part chemically is as good, better or the same as the hotter one?

The other contributors commented on the supplier having suggestions, well the suppliers was not very helpful.

I would also like to know, when the plastic is hot (> 260F), if it were to come into contact with ambient air, would that cause any reactions that might generate bubbles?

Thanks so much for your help, it is very hard to find anyone to ask about this stuff.

Thanks;

OleTechGuy

Register to Reply
Power-User
Canada - Member - New Member

Join Date: Feb 2006
Location: Richmond Hill, Ontario (North Greater Toronto Area), Canada
Posts: 240
Good Answers: 5
#8
In reply to #5

Re: Can you "Cook" Plastic too long?

02/12/2008 2:59 AM

"...the inside (which you can't normally see) was not as glossy...The part also was a little bit thicker."

I think the anwers lie in your observations. I would liken the rough inner surface to asphalt before the steamroller, thicker but with less strength.

On the one hand, a smooth inner surface is easier to clean.

On the other hand, a rough surface can be more abrasion and cut resistant.

So, cleaning aside, if your part is thick (strong) enough minus the roughness, no worries.

Otherwise, go back to Plan A.

__________________
You can have it good, fast or cheap. Pick two.
Register to Reply Score 1 for Off Topic
Active Contributor

Join Date: Feb 2008
Posts: 11
Good Answers: 2
#9
In reply to #5

Re: Can you "Cook" Plastic too long?

02/12/2008 9:08 AM

I think you got lots of comments about the finer points from several sources but no specif answers. Here we go: The problem is heat transfer, so the middle is not melted completely and thus not glossy nor consolidated (thicker part = lower density). This is perfectly fine if the part meets other functional requirements. If you need to worry about long term structural (fatigue) performance, you are in trouble not because of the molding but because you have chosen wrong plastic and the wrong process. As Rotomolded parts go, your seems fine. Aussie guy can probably tell you the thickness limitation of Rotomolding...cheers mate

Register to Reply
Commentator

Join Date: Feb 2008
Location: Somewhere south of Canada
Posts: 68
Good Answers: 1
#10
In reply to #9

Re: Can you "Cook" Plastic too long?

02/12/2008 11:28 AM

Damn drago, 10 points for keeping us to form, fit and function.

__________________
All this worldly wisdom was once the unamiable heresy of some wise man. -Thoreau
Register to Reply Score 2 for Off Topic
Power-User
Australia - Member - New Member Engineering Fields - Mechanical Engineering - New Member Engineering Fields - Marine Engineering - New Member

Join Date: Sep 2006
Posts: 451
Good Answers: 16
#6

Re: Can You Cook Plastic Too Long?

02/11/2008 11:39 PM

Roto moulding is a very special process for plastics. The main advantage is that you can do a large hollow item with out a core and with a consistent wall thickness. This is where it beats injection moulding and blow moulding. It is a very small niche market.

The wall thickness is determined by how much plastic powder is in the mould and how long you expose it to the correct heat. As the heat soaks through the mould it liquefies the plastic powder that is directly in contact with the mould. As the mould is rotating the powder that hasn't yet melted falls/rolls on to the next bit of the mould or the already plasticised plastic. In this way it gradually builds up the thickness of the plastic until all the powder is in the moulding. This where the prototyping comes in to determine how long the required heat soaking and subsequent cooling time should be.

It is also possible to use a half mould. Heat the half mould evenly to the required temperature. Dump a large quantity of plastic powder into the mould so that a far thicker layer than would be required is achieved. Let the heat soak into the plastic powder to achieve the required plastic thickness then invert the mould to remove excess powder and cool the mould.

This was a technique we used for making plastic kayaks. By making them in top and bottom halves a fortune was saved in shipping costs.

The dies that we used were usually cast aluminium that was highly polished. The main reason for this was the thermal conductivity.

The oven temperature was as per the plastic manufacturer's specification and the timing was the critical factor. By increasing the temperature you may gain a little in cycle time but you run the risk of burning the plastic and increase the need maintenance on the dies. Tooling cost are usually cheaper for rotational moulding so it can be used for short runs that would not be cost effective for injection moulding.

__________________
Make it so.
Register to Reply Score 1 for Good Answer
Power-User

Join Date: Jan 2008
Location: Durban, South Africa
Posts: 371
Good Answers: 7
#7

Re: Can You Cook Plastic Too Long?

02/12/2008 2:30 AM

Depends to some degree upon whether the Plastic is a thermoplast or a thermoset. Most roto molding I have met prefer the thermoplast. These contain a plasticizer which is a liquid with a high boiling point but is volatile. Using thermplast you need to have the temperature rise to a point at which the solid plastic dissolves into the plasticizer. In this way the viscosity will drop on initial heating and then increase as the dissolution takes place. Once complete dissolution is acheived you are at an end point and the mold can be cooled. Heating for too long can cause the plasticizer to volatilise too high a temperature will speed up the loss. Best temperature can be evaluated by putting a blob of plastic onto a preheated plate and after a short time to be determined experimentally tilt the plate to 45 degrees the run down distance will give measure of the time needed for the plastic solution to have formed as it will get more viscous. Over-heating of any plastic is inadvisable, a waste of energy & time.

__________________
You can always tell the pioneers - they are the ones with arrows in their backs.
Register to Reply Score 1 for Good Answer
Register to Reply 10 comments

Good Answers:

These comments received enough positive votes to make them "good answers".

"Almost" Good Answers:

Check out these comments that don't yet have enough votes to be "official" good answers and, if you agree with them, vote them!
Copy to Clipboard

Users who posted comments:

Ben Bonsens (2); BlueAussieBoy (1); dragothecompositesguy (2); hazman (1); JohnDG (1); Munky (1); OleTechGuy (1); Sparkstation (1)

Previous in Forum: crystal structures   Next in Forum: Two-Phase Heat Exchanger

Advertisement