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Commentator

Join Date: Nov 2007
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Ph Sensor

02/15/2008 12:45 AM

Hi every one,

the place iam working is a chemical factory, we have Ph critical reactions here. Ph electrode and transmitter of mettler toledo. are used. We generally perform a two point calibration using two buffer solution of 4.01 and 6.86Ph. How do i ensure that the Ph is varying linearly over 0 to 14 range. How to adjust the slope in case of any deviation.

One more question sirs, does Ph electrode show any difference in its output mv when subjected to Electromagnetic Interference or placed in proximity to a Cell Phone.

Thank you

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#1

Re: Ph sensor

02/15/2008 3:46 AM

Is it linear.... this shouldn't matter.. the point of a control system is to control therefore your ph shouldn't vary over the 0 to 14 range, it should hunt slightly around the control level according to the hysteresis and reaction time of the control system.

(I don't think it is linear...but I don't actually know....)

I wouldn't think a Cell Phone would effect it...after all the instrumentation should meet EMI regulations.
It would be easy enough to test it..... observe the reading while someone goes near with a cell phone.
I'd be more worried about some maintenance guy using an arc welder in the vicinity!
Del

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#2

Re: Ph sensor

02/15/2008 5:46 AM

<...How do i ensure that the Ph is varying linearly over 0 to 14 range....>

The manufacturers have already done this and type-tested the instrument. Refer to their operation and maintenance manual. Del has correctly pointed out that, if operating at a fixed pH setpoint, there is no need to vary the pH over 0-14 to ensure this. Further, buffering at 4.01 and 6.86 establishes a high level of confidence that the equipment is working correctly, as any errors will show up during the buffering procedure.

<...How to adjust the slope in case of any deviation....>

The slope is, from memory, around 59mV per pH unit and this figure varies with temperature. It doesn't need "adjusting", as it were, as there is nothing to adjust.

If there were to be some sort of adjustment facility on the instrument, and that adjustment were used while a reaction were proceeding, then it would obviate the need for a calibration procedure with buffers at pH 4.01 and 6.86, and the reaction products would be otherwise than that intended.

Here's a little story. A major photographic materials company went through this question 25 years ago in pursuit of quality enhancements. The problem was that the instrument used had an on-board slope adjustment knob, which got used to "make the results come out right". The instrument was also used to extend the operation beyond what was considered a limit for the calibration procedure as, after this time, the procedure was for the electroded to be removed, cleaned and a repeat buffering/calibration procedure to be carried out. As a result of not following established correct procedures in response to production pressures, the reaction product went out-of-specification! But they got it out the door!! But that which did go out the door wrong always came back for re-work, adding to the production pressures!!! Their solution was to embrace the calibration and time-of-use procedure within a custom, electronically pre-programmed instrument that inhibited the operator from proceeding with a reaction and actually making something that was out-of-specification. Their approach was commendable and effected a major improvement in business performance, with more, correct product being shipped and a decline in re-work to almost zero.

<...does Ph electrode show any difference in its output mv when subjected to Electromagnetic Interference or placed in proximity to a Cell Phone...>

This is something that can be determined by experiment locally, with an off-line model of the reaction in question. It is likely that the effect will be very small if the electrode is in contact with the reaction mixture and the equipment has been correctly assembled, as the pH signal is a DC voltage, albeit of high impedance.

Consider banning the carrying and use of cell-phones in the reaction area should the concern be valid.

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#5
In reply to #2

Re: Ph sensor

02/18/2008 11:50 AM

Good answer PWS. I also would also like to point out the yours was the only post that correctly used small p and capital H. pH.

It is a constant reminder that we are measuring the negative log of the hydrogen ion concentration. or a range of 1 to 14,0000,000,000,000. It seams we get lost looking through the window the instrument lets us view the process through.

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#3

Re: Ph sensor

02/15/2008 7:40 AM

How do i ensure that the Ph is varying linearly over 0 to 14 range

When I first played with pH, I also asked this question. We calibrated with pH 4 and pH 7 and assumed that the reading above pH 7 would be accurate as well.

Just to reassure myself, I had them purchase a pH 10 buffer solution. After doing the usual calibration with 4 and 7, I checked the reading with the pH 10 buffer. Watta ya know! It read correctly! It took more time to settle at pH 10 but it did read correctly.

How to adjust the slope in case of any deviation

Most pH meters I've seen have a facility for making adjustments, usually a zero and span. This can be two potentiometers or, in the case of digital instruments, a couple of buttons.

does Ph electrode show any difference in its output mv when subjected to Electromagnetic Interference

I haven't tried this with pH meters or probes but I've noticed that some instruments can be affected if the phone is right next to the instrument (the instrument's cover needs to be off too).

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#4

Re: Ph Sensor

02/16/2008 2:19 PM

Hi My name is Edgar ,firsth I request excuses because my english is¨t good!! I hope that my opinion will can help you!!!. I work in electronic design and I was working with electromagnetic sources

about the celular phone magnetic interference...

The platinum and titanium is most frecuently used by manufactured electrodes. These materials isnt magnetizable because are paramagnetic (its magnetic relative permeability is equal or aproximatly equal to 1 ).

If you are talking about the electronics circuits sensor thats another thing.....if those circuits havent a correctly proteccion for EMI (electromagnetic interference) you can sure that the magnetic interference exist!!!. But dont worry you can comprobate this with a experiment. Probe the Ph about a sustance (good Know PH)and keep close the celular. Then see the result.

You need to know that the interference only exist when the electromagnetic radiation source is closely together. The electric cable (line voltaje cable) cause more interference that the celular phone, the computers and TVs monitors also cause electromagnetic interference, the proximity access control antennas (texas instruments, siemens HID etc), flouresent halogen lamps, they cause interference.

Other experiment is use a compas aroun the place to protect. if note a desviation in the compas then you have a EMI.

If you note EMI and the EMI source cant go you can make a EMI shield.

Prove

1. put the circuit in close a stainless steel box and conected this box (externaly) to physical ground. The compas inside the box cant get desviation.

2. If the number one point ist enough put the circuit in close a steel (no stainless steel) concretly is a ¨oxidable steel¨ (in Mexico we called ¨lamina negra¨). The compas inside the box cant get desviation. This kind of steel have a diamagnetic element ( is not magnetizable and its opositive to the magnetic field ). the magnetic field cant to penetrate this material (and obviusly the box).

Preferent the box will be externaly conected to physical ground.

Good luck!!!

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#6

Re: Ph Sensor

03/04/2008 10:26 PM

Hi,

As the topic is about the pH Sensor, I would like to add my question here.

We have a pH Electrode dipped in our Aqueous Washing Tank with

Ultrasonic Frequency at 40kHz and 70% of 2kW Power Rating.

Water Temperature is at 55°C ± 5°C.

My problem is the the glass sensor always breaks. We are using signet pH Electrode.

My initial thought is that, the glass breaks due to the ultrasonic wave in the tank?

Is this correct?

And is there any ways to protect the glass from breaking?

I'm also thinking of putting the sensor in-line and not in the tank itself but the cost my concern.

Any help/advice please?

Thanks..

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#7
In reply to #6

Re: Ph Sensor

03/05/2008 7:26 PM

I've used pH sensors with ultrasonic cleaning devices right next to them. The purpose of the device was specifically to keep the probe clean, not to clean anything else. I don't know precisely what the power rating of the device was but it probably wasn't 2kW.

It's possible that your pH probe isn't designed to handle such high levels of ultrasonic power. I'd advice trying a different type of probe, like a plastic lined one, instead of a glass type. Inquire from your supplier if they have any alternatives.

If I guess right, you just bought a pH probe and stuck in the tank without informing the supplier of what you were going to use it for.

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#8
In reply to #7

Re: Ph Sensor

03/05/2008 7:41 PM

Hi Vulcan,

Thanks. But the probe has been there before i join the company so i don't know the history. Now I'm trying to correct this to avoid losses and interuption to our washing line.

I'll try to get some plastic types.

I have some from mettler toledo which they say will not break coz their glass is thicker but i'm not that confident.

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#9
In reply to #8

Re: Ph Sensor

03/05/2008 11:00 PM

i'm not that confident

I wouldn't be confident either. Here's what you can do.

If they give you assurance that it will survive for, say, three months, get it in writing and have them put it in. They have to be the one to do it so that they can't claim that you installed it improperly. If it survives the specified time period, you pay them. If it breaks before that time, they take it as a loss.

We call these "trial orders". We never pay them until it proves itself. If it doesn't work, they just get their equipment back (in whatever condition it is in) and walk away with a loss. It's not applicable in all cases but it works.

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#11
In reply to #9

Re: Ph Sensor

03/10/2008 12:28 AM

Vulcan,

Ok. I'll do that. Maybe they can consider some trial before i really purchase there product.

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Commentator

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#10

Re: Ph Sensor

03/09/2008 3:13 AM

Based on this discussion i would like to ask the forum members, we are actualy facing a similar situation in our factory. we are using using mettler toledo glass ph electrode which often break while removing them and dipping. this has to be done frequently to ensure correctness. Is there any alternative to this. I mean any non-contactive type ph electrode or a much rugged one other than glass.

thnx

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#12
In reply to #10

Re: Ph Sensor

03/10/2008 12:36 AM

Hi Srao,

Since your present supplier is mettler toledo, i see some pH Electrode that is more rugged.

You can check there latest Catalogue.

BTW, what model are you currently using? Mettler Toledo as k me to used this model:

Inpro3250

and the electrode is not all the way dipped in, right?

Coz mine is always in the tank with ultrasonic transducer thus it breaks

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