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Leaking Pipes

03/26/2008 9:05 AM

We are having a lot of problems with pin holes popping up throughout our copper piping in our institution. Our water treatment expert says this is caused by over softening our water supply. Is it possible to over soften the water? Our hardness is 0ppm and we are running recirculation pumps throughout. I was thinking it might be more of a grounding issue causing an electrolysis type problem. Does any one have any suggestions on what might be causing our problem?

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#1

Re: Leaking Pipes

03/26/2008 9:35 AM

What is the pH? Of what quality is the water - is it for drinking, for example? What other species are dissolved in it? What is the pressure rating of the pipes and what is the maximum operating pressure and temperature?

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#6
In reply to #1

Re: Leaking Pipes

03/26/2008 1:02 PM

Our ph is 7.58. Operating pressure is 60psi. Temperature is around 60*F. This is potable water coming in from the city. It may contain parts of iron, sulfur, and lime.

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#2

Re: Leaking Pipes

03/26/2008 11:23 AM

I have run in to this in the past. In the case I am thinking of it was caused by cavitation erosion caused by air in the system. The bursting of tiny air bubbles near the pipe surface slowly erodes the copper. Does the damage occur near corners or junctions or a change in flow? Were a pressure change is occuring.

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#3
In reply to #2

Re: Leaking Pipes

03/26/2008 11:51 AM

The corners get beat up pretty bad but it also happens in the middle of long stretches of pipe. How did you address the problem?

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#4
In reply to #3

Re: Leaking Pipes

03/26/2008 12:08 PM

That would make sense long stretches of tubing vibrate at high freq. causing pressure drops. They added a Deaeration unit to our system. It looks like a small pressure tank in line after the pump. A good industrial plumbing contractor should have more answers on the problem.

I hope this helps I am no plumbing expert. Please let me know what you find out.

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#5
In reply to #4

Re: Leaking Pipes

03/26/2008 12:57 PM

Thanks for the help.

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#17
In reply to #2

Re: Leaking Pipes

03/28/2008 3:31 AM

Hi, repair71!

And a big fat welcome to CR4. Great to have you aboard.

Mark

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#19
In reply to #17

Re: Leaking Pipes

03/28/2008 10:32 AM

Thanks Honored to be here. Don't know if I will be much help to anyone, feeling kinda selfish because I will learn much more than I will help.

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#7

Re: Leaking Pipes

03/26/2008 11:34 PM

How many years have the coppers pipes been in use? I have been correcting these pinhole leaks in old (40+ years) copper lines for a few years. The water is not softened, but is the hard type right out of the city supply lines. Apparently, internal corrosion is the culprit, but I don't know if it is the result of grounding or lack thereof. Might be just the age of the pipes, so it looks like a gold mine is coming for the plumbers, and water cleanup folks when millions of copper pipes pop.

Here is a site with a dissertation on the pinhole problem... http://www.toolbase.org/Building-Systems/Plumbing/copper-pinhole-leaks

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#10
In reply to #7

Re: Leaking Pipes

03/27/2008 6:58 AM

This is a newer facilility, about 7 years old.

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#8

Re: Leaking Pipes

03/27/2008 12:23 AM

Good day.

I have worked some pin hole problems in copper pipes. Usually caused by the water eroding the pipes by lack of reaming the pipe at the joints causing turbulent flow or localized errosion. It's also caused by the flow of the water simply eroding the pipe. I have recently installed a system designed to prevent any future leaks, unfortunately leaving you to deal with the ones you have.

This is the Parafos system, I haven't been able to find a website but it is the same system we used. The buildings we put it in have been leak free a year after we installed it.

http://www.meatandpoultryonline.com/Content/ProductShowcase/product.asp?DocID=260cc0e8-0375-11d5-a770-00d0b7694f32

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#9

Re: Leaking Pipes

03/27/2008 1:57 AM

You maybe smarter then your "water treatment" expert. Your being generous with the "expert term" because most of them are expert blamers. Check the velocity of your water, replacement pumps are sometimes oversized causing premature failure in the joints. Certainly you can have a grounding issue, do some cathodic research. Are you talking about a domestic hot water system or a heating system? Please provide more info on the system. Do you have Di-electric unions anywhere?

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#11

Re: Leaking Pipes

03/27/2008 10:27 AM

If you are getting pin holes in your copper tubing.........dare I say it...........it is unlikely that it is caused by stray electric current or poor grounding.

It is more likely to be caused by pitting which may be caused by one or more of several reasons, some of which are:-

1. Contaminated water....varios salts, including water softeners.

2. Differential aeration.

3. Poor wokmanship............e.g. excessive use of fluxes.

4. Excessive water velocities, also low water velocities can cause major pitting in some piping materials.

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#12

Re: Leaking Pipes

03/27/2008 10:50 AM

Electrolysis may be a factor, but it would likely occur where the copper meets another metal or ground, not in the middle of a run. Although turbulence may be the cause, those usually occur within 5-10 pipe diameters of a flow disturbance. After that, laminar flow develops and the turbulence disappears. Again, that would not account for leaks in the middle of a continuous run. Don't completely discount your expert's opinion. Pitting corrosion is a well-known cause of major headaches for homeowners and facility managers.

Take a look at this tech note. More information is available from the Copper Data Center.

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#15
In reply to #12

Re: Leaking Pipes

03/27/2008 9:50 PM

Electrolysis may be a factor,

Electrolysis, when talking of corrosion. Please, please do not use that word, there is no such animal..................it is either galvanic action, or stray electric current.

You will never find the word in reputable literature on corrosion, if it is there, it is only to correct the meaning of the term............ugh...........electrolysis.

Galvanic action or stray electric current is not likely to cause pinholes in the pipework.

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#21
In reply to #15

Re: Leaking Pipes

03/28/2008 5:30 PM

Mobi,

I agree that electrolysis is not a mechanism of corrosion. If you review my earlier post you will see that I never stated or implied such a thing. I reviewed a variety of potential causes of the pinholes. Corrosion is one possibility, but by no means is it the only one. I also discussed turbulence, which results in erosion, not corrosion. Another possible cause is electrolysis, defined as:

1.

Physical Chemistry. the passage of an electric current through an electrolyte with subsequent migration of positively and negatively charged ions to the negative and positive electrodes.

The effect of electrolysis can be similar to galvanic action. The mechanism of electrolysis differs in that the ion migration is driven by an external electric field.

If, in fact, there is a grounding problem in the facility which results in a "stray electric current" through the pipe and water, the effect on the pipe would indeed be electrolysis, not corrosion.

Further, the conclusion of my earlier post clearly states that I do not think that electrolysis was the likely cause, but a rather commonly encountered form of pitting corrosion, as described on the linked sites. We would be derelict in our professional responsibilities, however, not to consider all reasonable possibilities.

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#22
In reply to #21

Re: Leaking Pipes

03/29/2008 11:17 AM

Put simply Electrolysis is the breaking down of the electrolyte, which maybe accompanied by gassing. (As in the operation of a battery) IT IS NOT A FORM OF CORROSION it is either.

Galvanic action and stray electric current are WRONGLY called electrolysis. Galvanic action can also be called electrolytic corrosion.

As I pointed out before read a REPUTABLE book on corrosion, written by metallurgists, whose expertise is corrosion.

One can also remove metals from ore either chemically or electrolytically.

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#13

Re: Leaking Pipes

03/27/2008 4:22 PM

You might want to look at water chemistry and also the possibility of microbial action. We had this happen on some copper sprinkler piping, which was stagnant most of the time, which would rule out cavitation and erosion issues. Also, since iron is anodic to copper and thus would corrode preferentially to the copper in a galvanic corrosion situation, it was felt that in our case, galvanic corrosion between iron and copper pipes was not a likely cause of the problem. I found that the pinhole corrosion had two basic causes: water chemistry, and microbiologically influenced corrosion (MIC). Certain aspects of the chemical composition of the water make it aggressive to copper piping, causing pitting, and eventually pinhole leaks. Chlorides, sulfates, sulfates, acidity, and dissolved oxygen are among the most corrosive of the water constituents.

MIC occurs when certain bacteria grow inside the pipe, and excrete products that accelerate corrosion at isolated locations, causing pitting at those locations. MIC is accompanied by relatively heavy deposits inside the pipe (green deposits in copper pipes, and black or orange deposits in ferrous pipe). MIC was reported to cause problems in sprinkler systems because the water is stagnant for long periods of time, which allows a long residence time for bacteria; also the corrosion products can break loose and plug the sprinkler heads.

Water Chemistry

The water chemistry is felt to be a likely reason for the observed corrosion in the piping. Water can be classified as either scale-forming or non-scaling, where scaling is the formation of a protective coating of deposits on the inside of the pipe. Without the formation of scale to coat and protect the pipe interior, corrosion can proceed unhindered. Two industry standards for evaluating the scaling tendency of waters are the Ryznar and Langelier Indices. These indices are computed based on measurements of the pH, Total Dissolved Solids (TDS), temperature, alkalinity and hardness. Langelier Indices less than 0.0 and Ryznar Indices greater than 7.0 indicate greater corrosive tendencies. Lower pH indicates greater acidity and thus a greater corrosive tendency. Chlorides, sulfates, sulfates, dissolved oxygen, and free CO2 also tend to promote corrosion. The presence of other dissolved metals can affect the formation of corrosion cells localized to individual pits. The following table presents a water chemistry scheme recommended to minimize corrosion:

Recommended Water Chemistry

Parameter

Value

PH>8.3
Chlorides<50 mg/l
Sulfates<100 mg/l
Aluminum<0.3 mg/l
Iron<0.3 mg/l
Manganese<0.1 mg/l
Langelier Index>0
Ryznar Index<6
Alk/(Cl + SO

4)

>5 mg/l
Alkalinity>40 mg/l
Calcium (calcium carbonate)>40 mg/l
Precipitation Potential>4-10 mg/l

Finally, one might want to consider the thickness of the piping. Type M copper is thinner and may thus fail sooner. Engineering studies indicate that the Type M copper tubing would have a time-to-failure of about 70 to 75% that of Type L, i.e. it would last about 70 to 75% as long as the thicker type L. A thicker piping would not prevent corrosion, it would only postpone it.

Please excuse the long post, and the fact that it is geared towards sprinkler piping which is stagnant most of the time, however, if there are some nuggets of info here that can help you, then all well and good.

Regards

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#14
In reply to #13

Re: Leaking Pipes

03/27/2008 4:59 PM

Excellent post, JDknut. What can be done to prevent MIC?

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#16

Re: Leaking Pipes

03/28/2008 3:28 AM

Hi, LockedUp!

Several answers come to mind. I suspect, however, that the small holes are not an escape attempt, since (a) they are small, and (b) the water pipes are also (probably) small.

However, just in case I'd be looking for another inmate, probably in shop, working on a shrinking ray and a mini submarine.

It stands to reason, although I'd never heard of this holing phenomenon before, that removing trace minerals from the water supply side that runs through copper piping, and as a result possibly combining more unadulterated copper in the --whatever small-- amount of scale it produces after softening, will leave the water actively ionic enough to leach material from the piping in some places and deposit it in others.

So, I'm just theorizing...Laminar flows might subject straight pipe length sections to corrosion in this way due to the lessened activity at the flow perimeter; and soldered pipe joints might be more likely to undergo buildup due to edge-induced turbidity-encouraged redistribution of the charges.

Next, it might be important to determine which cell block the plumber is from...

On the discharge side, holing is eventually almost always present in copper piping due to either low or high PH waste running through the pipe, especially where there is partial blockage causing eddying or pools of backup inside the pipe where ionization activity can run rampant.

In either case, I find softened water to be a royal pain in the butt, since:

drinking it robs your body of trace mineral intake from its natural source (drinking water);

and washing with it leaves a soapy feel one continues to wash off one's body parts forever with soft water

or washing the soapiness -completely- off anything else with softened water is a difficult chore.

Losing the water softening system could be better all around. Just a personal bias. I know some people love 'em.

Four years ago, I asked my then 92 and 96 year-old parents what they attributed their longevity to. Both immediately and candidly responded that they had decided their long lives could be attributed to drinking from the normal tap water supply. (But at least part of it had to be the two dozen -it seemed- vitamins and minerals they were each swallowing down with that water daily, plus various juices, milk, diet supplement drinks, and tea they were also seen drinking every day.)

Mark





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#26
In reply to #16

Re: Leaking Pipes

04/02/2008 5:56 PM

However, just in case I'd be looking for another inmate, probably in shop, working on a shrinking ray and a mini submarine.

And the holes are from mini torpedoes?

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#18

Re: Leaking Pipes

03/28/2008 3:57 AM

Hi LockedUP!

By gosh, I just noticed that you're a new member in here!

I think I lost sight of that fact due to the great keffufle your first post engendered in the CR4 following.

Well, done!

And it's just a pleasure to have you join us.

Keep up the stimulating input, and never forget "Quando omni flunkus moritatus".

Mark

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#20
In reply to #18

Re: Leaking Pipes

03/28/2008 2:42 PM

Pleasure to be here. I stumbled on the site doing research for an engineering class and found it to be very helpful at my job. I appreciate all the great ideas I have received.

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#23

Re: Leaking Pipes

04/01/2008 9:44 AM

yes, water can be too "soft" most dionizer systems require that the piping from the unit to the holding tank be made of 304 SS, iron piping will dissolve in the water.

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#24

Re: Leaking Pipes

04/01/2008 2:03 PM

I worked in a facility that used D/I water in various processes and tapped into it to feed industrial humidifiers serving environmental chambers. None of the tubing used to feed the D/I (de-ionized) water was copper. It was all plastic tubing, presumably because the D/I water attacks any metal in encounters as it is naturally metal free and seeks to entrain metallic elements within itself. If you are running 0ppm hardness water through the copper, I would suggest going to some form of plastic piping, consult with a plumber or pipefitter!

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#25
In reply to #24

Re: Leaking Pipes

04/01/2008 10:58 PM

Welcome Richard....It's about time you chimed in.

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#27
In reply to #25

Re: Leaking Pipes

04/11/2008 5:48 PM

Yeah, you wish it was Richard CTH.

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#28
In reply to #27

Re: Leaking Pipes

04/12/2008 4:27 AM

Hi, Great Basin!

I just want to ad my 'Welcome' to MTHBG's.

Great to have you here, and looking forward to seeing more of you.

Mark

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