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Regarding Unsaturated Polyster Resin

08/16/2010 1:26 AM

I'm doing some casting work with unsaturated polyster resin. The shop from where I bought these chemical that shop owner told me to take 3% Cobalt as aceleator and 1.5 % hardner (i.e. MEKP). But while curing, it is getting cracks. I'd like to know exact percentage of hardner (i.e. MEKP) and cobalt (Acceleator) for 550 ml quantity of base resin. Could you please help me friends.

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#1

Re: Regarding Unsaturated Polyster Resin

08/16/2010 2:48 AM

Contact the manufacturer directly.

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#2

Re: Regarding Unsaturated Polyster Resin

08/16/2010 3:39 AM

If it's cracking, you are using too much hardner and/or accelerator or making too big of a batch.

Reduce the concentration of both until satisfactory results are obtained.

Or, call the manufacturer.

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#3

Re: Regarding Unsaturated Polyster Resin

08/16/2010 3:19 PM

Curing and applicalion temperature can have an effect too

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#4
In reply to #3

Re: Regarding Unsaturated Polyster Resin

08/16/2010 3:25 PM

And on and on. Polyester is especially difficult to trouble shoot long distance due to all the variables. It's not like a two part epoxy.

My advice is start out under-catalyzed and work your way up to adequate cure in small increments.

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#5

Re: Regarding Unsaturated Polyster Resin

08/17/2010 2:37 AM

3% Cobalt isn't too high ... use a little less to to slow the volume expansion & subsequent shrink RATE (1.5-2%) ... and make sure you mix it really well. The MEKP is correct. Insulate the castings for 12 hours minimum ... to slow the shrink rate.

If you have an enclosed interior volume, you need to leave a hole in it somewhere ... or when it heats up, it will really expand ... then shrink as it cools ... and crack ... if I were to bet I think that is the real problem. It will shrink by about 2% already ... so if it expands with entrapped air, it will shrink by two different means and crack like crazy.

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#6

Re: Regarding Unsaturated Polyster Resin

08/17/2010 8:59 AM

You need to cut down to 1.5 to 2 % of Cobalt and 1 to 1.25 MEKP in 550 ml quantity of base resin.

After casting cover it and let it shrink slowly overnight before opening the cover and you will be okay

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#7

Re: Regarding Unsaturated Polyster Resin

08/17/2010 11:24 AM

May I slip in a side question, I don't want to hijack a thread?

What is the difference between saturated and unsaturated polyester? They have different numbers in my import tariff and polyester is the only plastic that asks this question. Is there an easy way to tell them apart? (Something I can ask a non-chemist)

Again sorry for the interuption.

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Re: Regarding Unsaturated Polyster Resin

08/17/2010 12:52 PM

An unsaturated polyester is a polymer chain containing alternating dibasic acid and glycol monomers linked together by ester bonds. The unsaturation comes from the incorporation of a dibasic acid that contains a double bond, typically maleic acid formed by the ring opening of maleic anhydride. As the concentration of maleic acid in the polyester chain increases, so does the resin's reactivity. Several different glycols and/or dibasic acids can be copolymerized into the polymer chain. At the end of the reaction, the polyester resin is blended with a reactive diluent, typically styrene. The reactive diluent contains a vinyl double bond and serves to reduce the viscosity of the polyester resin so that it can be pumped and processed. Hence, the resin manufacturer can produce a wide variety of polyester resins with differing structures, reactivities, and molecular weights, which impart different properties to the resin and the final molded product.

Now,why are they classified differently? I don't know, and I can't even find the excellent site where I copied the information above. If I find it, I'll put it up here.

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