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For pipe joints like SS elbow dia 76mm SMS, SS unions, Tees, concentric reducers what material should i use 304, 304L, 316, 316L?
It depends on how much corrosion resistance is needed for the fluid being carried, and then on the budget.
If you are meaning by SMS - Sanitary Manufacturing Standards which are piping with highly polished surfaces then I would suggest you use SS-316 / SS-316L. This gives better resistance against acids.