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Calculation of Rp and Icorr Based on Cycle Usage

12/29/2012 5:50 AM

Dear All! Need your assistance!

I need to calculate polarization resistance (Rp) and corrosion rate (Icorr) based on the cycle usage.

I have initial data for E (mV) and i (mA). And i made calculations for Rp and Icorr.

Now i have cycle usage information: (Assuming a 20 year life, comment on the suitability for use based on a cycle usage of 24 hrs for 5 days per week operating for 40 weeks per year.)

But i do not understand how to calculate the Rp and icorr tying it in with the cycle usage.... Any guidance please on here! Thanks!

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#1

Re: Calculation of Rp and Icorr based on cycle usage

12/29/2012 9:43 AM

We still don't do homework.

Try: www.icorr.org

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#2

Re: Calculation of Rp and Icorr Based on Cycle Usage

12/30/2012 1:13 AM

You will need to buy oranges for 20 years, it is healthy.

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#6
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Re: Calculation of Rp and Icorr Based on Cycle Usage

12/31/2012 11:54 AM

Hey! I thought we were talking apples, and here you go bringing up oranges.

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#3

Re: Calculation of Rp and Icorr Based on Cycle Usage

12/30/2012 3:22 AM

The cycle usage of what exactly?

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#4

Re: Calculation of Rp and Icorr Based on Cycle Usage

12/30/2012 3:32 AM

The cycle usage of a carbon steel pressure vessel (autoclave) used for the vulcanization of rubber.

Assuming a 20 year life, cycle usage of 24 hrs for 5 days per week operating for 40 weeks per year.

I have calculated corrosion rate, which is: 4.87 µA/cm2 = 0.0565 mm/y thickness loss.

Now how do i tie it in with the above mentioned cycle usage? Do i need to account for 20 years or should i count for cycle usage, which is to be: (24*5)*40=4800 hrs in 1 year*20 years=96,000 hrs in 20 years. which is 10 years of operation, so 0.0565 mm/y*10=0.62 mm loss in 20 years of operation.

Am i right??? Thanks!

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#5
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Re: Calculation of Rp and Icorr Based on Cycle Usage

12/30/2012 5:31 AM

If the vessel is exposed continuously even in off cycle then assume the worst.

If the vessel is cleaned out totally and you can guarantee that corrosion will totally stop during off cycle then the other.

The latter of these two will require you to personally ensure that proper cleaning and corrosion inhibition is maintained during off time for the next 20 years to guarantee it though.

Always assume that the worst will happen.

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#7
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Re: Calculation of Rp and Icorr Based on Cycle Usage

12/31/2012 11:58 AM

Now that you did all the calculations, and your apples and oranges are sorted out, do you think that you might need to actually monitor corrosion with a corrosion monitor?

Sometimes even the best calculations do not cover all the conditions that could occur locally in such a vessel...but then neither will a corrosion probe that is sitting somewhere in the vessel, when the problem is on the other side of the vessel.

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#8
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Re: Calculation of Rp and Icorr Based on Cycle Usage

01/02/2013 3:35 AM

This is the sort of topic that needs to be discussed with the Engineer/Surveyor from the company providing burst indemnity insurance cover on the vessel. That dialogue is important, for it establishes the validity of the calculations for insurance cover purposes, the robustness of the design, the written scheme of examination and the routine inspection frequency once the vessel has been brought into use. Open that dialogue now/this morning/today/immediately, if not sooner.

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