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So far the sources of hydrogen we have looked at either require the consumption of large amounts of electricity or fossil fuels. If the resultant carbon byproducts are not stored in some long term geologically stable form all that is achieved is a relocation of the point the pollution and green house gasses are released.
One possible solution is to use hydrocarbons from plant materials and since the majority of the carbon in plants comes from the present atmosphere, rather than something that has been locked up underground for millions of years, they are close to being atmospherically neutral.
For various reasons these hydrocarbons are not suitable for use as a fuel and require further processing, like fermentation into ethanol, before they can be used as a fuel for engines. While most internal combustion engines can be made to run on alcohol it is not ideal and has numerous limitations and problems.
It is possible to extract energy directly from the sugars in the biomass produced by plants and by fermenting the sugars into alcohol you can power many internal combustion engines, but the overall efficiency is only about 20%. However, if the hydrogen is extracted the overall efficiency can increase to almost 60% and that translates into a reduction of the land area dedicated to growing fuel crops by up to 66%.
There are however some interesting technologies in the pipeline that show considerable potential:
· 2,5-demethylfuran DMF has an energy density around 40% higher than ethanol and there is currently a process being developed by researchers at the University of Wisconsin.
· Partial Oxidation of Alcohol shows potential for converting alcohol to hydrogen in reactors that are compact enough to be used at the point of consumption. This enables the fuel to be stored as alcohol and then converted to H2 By converting the alcohol to H2 at the point of consumption you minimize the problems associated with the storage of H2.
There are a host of other methods of extracting H2 from alcohol but they are generally not that efficient and require large and complex treatment plants. This means that they can't be used at the point of consumption and leaves us with the usual problems of handling and storing H2.
The concept of biomass to H2 sounds promising but it is never that simple and there are always complications. Probably the most important is that if we do switch to utilizing a crop based fuel like alcohol or hydrogen from alcohol, how will that affect the world's food production? There have already been serious repercussions with the use of corn to create fuel and the production of palm oil for fuel ended up with the clearing of large tracts of virgin rainforest.
Is it possible to generate enough fuel from plants to replace our current consumption of fossil fuels? If we do expand the concept what effect will it have on the world's food production and how much additional forest will need to be cleared? Given that our demand on fossil fuels is increasing day by day and that reserves are finite can we afford not to develop technologies like this?
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