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Rainbow on Photo Voltaic.

03/08/2011 6:58 PM

Dear all! I have a project in Colorado Technical University; it's about improving efficiency of current solar-power systems. My idea is "compress" the sunlight with parabolic mirror (like they do it on thermal solar-power plants heating oil inside the tubing). However, I would modify the tubing covering it with a small mirror of the same shape and with the same center-point of parabola (perhaps, y=0.5) as the big one so that it would reflect light back toward the center of the big mirror. There is a prism there in the slot between two parts of the big mirror that would split the sunlight to its spectrums from Infra-Red to Ultra-Violet. Tracking system will keep the prism in the shade from the sun, but powerful light reflected first from the big mirror to the small and then reflected back from the small mirror altogether will come through the prism splitting into spectrums.

I believe that the small mirror will get very hot being capable of heating the oil inside it (I think so because I have a steel mirror-like bumper on my van, and it gets very hot even under not concentrated sunlight). The reflected light will split into spectrums and come upon different kinds of photovoltaic. The reason for that is that different materials used for photovoltaic will work best on specific wave-lengths of the sunlight and will not work on other spectrums.

I want to ask you several questions:

1. The Sun light provides the Earth with light and heat; it consists of variety of different rays. Which rays produce heat and which are good to produce electricity with photovoltaic? Some people say that only IR rays produce heat (that's what my teacher said in my high school), but others say that it is a common misconception. What do you think about this?

2. Is glass a good absorbent or blocker for Ultra-Violet rays?

3. Can Infra-Red rays be used on photovoltaic? If so, what kind of material shall be used?

Sorry for my graphics; I am not good on it, but you can see the main point: sunlight hitting big mirror at any point is reflected to the common center of two mirrors (y=0.5); on its way to the center it hits the small mirror which is combined with oil tubing and reflected toward the prism where the light is "separated" and goes to different kinds of PV receptors. Do not care much of the proportions on my drawing.

Thank you, fellows, in advance for your help!

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#1

Re: Rainbow on Photo Voltaic.

03/08/2011 8:48 PM

I found the graph below from the following link:

http://citeseerx.ist.psu.edu/viewdoc/download;jsessionid=CD3A2BD5204BF4341D38D1F5738062C5?doi=10.1.1.40.3918&rep=rep1&type=pdf

As you can see, solar cells respond to light from wavelengths in the range of 380 to about 1300 nanometers. So yes, visible [380 to 760 nm] and near-IR light will excite solar cells. (Note that IR to wavelengths of 1300 is not really 'heat' radiation, so it is generally referred to as 'near-IR'.) 'Heat' IR at about 2 microns and higher (2000 nm +) will not excite solar cells.

Q1. The Sun light provides the Earth with light and heat; it consists of variety of different rays. Which rays produce heat and which are good to produce electricity with photovoltaic? Some people say that only IR rays produce heat (that's what my teacher said in my high school), but others say that it is a common misconception. What do you think about this?

A1: For the first part of the answer, see above. Any wavelength of energy from gamma to microwave can produce heat. (You do use a microwave oven right?) It's a matter of absorption and conversion of the energy into heat. IR from roughly 2 to 200+ microns is directly felt as 'heat'.

Q2. Is glass a good absorbent or blocker for Ultra-Violet rays?

A2: Most glass and some plastics will block UV by absorption, depending on the thickness. For common glass, like soda-lime window glass, you need about 1/8th inch to block unfocused sunlight. The absorption process is logarithmic, so more intense light will require more glass. (Look up Beer's Law.)

Q3. Can Infra-Red rays be used on photovoltaic? If so, what kind of material shall be used?

A3: Yes, as you can see from the graph above. The spectral response of the solar cell depends on the type of material used for the solar cell.

You ought to look up Cassegrain and Gregorian telescope optical systems. Your sketch is similar to a telescope system, so by looking up info on these optical systems you can avoid errors and perhaps improve the system you are envisioning.

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#2
In reply to #1

Re: Rainbow on Photo Voltaic.

03/09/2011 12:31 AM

Thanks for help!

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#13
In reply to #2

Re: Rainbow on Photo Voltaic.

03/10/2011 5:28 PM

You're welcome. Interesting idea; hope you get good results.

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#6
In reply to #1

Re: Rainbow on Photo Voltaic.

03/10/2011 12:59 AM

Usbport that is a very nice reply to repnitskiya. Greg

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#14
In reply to #6

Re: Rainbow on Photo Voltaic.

03/10/2011 5:28 PM

Thanks!

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#3

Re: Rainbow on Photo Voltaic.

03/09/2011 11:30 PM

I really like this idea. I think the main challenge is that you've created a very complex system of solar cells. Each one is a current limiter, and the spectrum is going to change throughout the day. That can be overcome or accepted. The enemy in concentrated solar cells is heat. I don't know what the materials are that would make this prism and mirror work, but I applaud your creativity, and you should look at how to make the heat do work to gain more efficiency.

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#7
In reply to #3

Re: Rainbow on Photo Voltaic.

03/10/2011 1:42 AM

Sorry, I forgot to tell that the mirror will be moved during the day by two-axis tracking system following the sun, like a sunflower does. Now they already use photovoltaic on medium and even high concentrated systems; lower concentration sometimes does not require coolant, but high-concentrated systems, like Zenith (http://www.zenithsolar.com/), need water or some other coolant. Photovoltaic can be hot (up to some point) and still work well. The small mirror would be made of metal (maybe bronze or copper covered with nickel or chrome) with coolant (water or, better oil for higher temperature, depending on needs) inside, so it will not make red-hot.

Thank you for your comment!

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#4

Re: Rainbow on Photo Voltaic.

03/09/2011 11:59 PM

You may want to consider the effect of heat on PV efficiency. Google "The Impact of Ambient Temperature on the Efficiency of Photovoltaic Cells". Seems to be a paper with some quick data.

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#5

Re: Rainbow on Photo Voltaic.

03/10/2011 12:48 AM

Just wanted to throw another idea in for your consideration and / or analysis...

Have you considered using a dichroic mirror to separate the heat and light parts of the spectrum?

If heat (IR) is the enemy and visible spectrum is good for solar PV cells then I wonder if a dichroic reflector similar to that found on halogen dichroic lamps may help? These are designed to reflect a focussed beam of light from the lamp but allow IR to pass through, so you get a spot light effect in front of the lamp and avoid spot heating etc.

With such a dichroic reflector used near the focal point of the large mirror you can have solar PV placed in front of the reflector and an IR absorbent (black anodised?) collector behind the mirror, efficiently collecting energy accross the whole range.

This has the added bonus of improving the efficiency of the solar PV too by not heating it so much with IR.

You might even consider different types of dichroic prismatically arranged to reflect different parts of the visible spectrum in different directions to land on PV collectors of the most efficient type for each part of the spectrum. I envisage this idea might work in a similar way to LCD video projectors which separate the red, green and blue parts of the visible spectrum for individual colour processing before it's re-assembled back into a single light path again for final projection as a 'full colour' image.

Kind regards,

Chris

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#8
In reply to #5

Re: Rainbow on Photo Voltaic.

03/10/2011 3:01 AM

Yes, I was thinking about something like dichroic mirror when looking at DVD on light; it also creates 'rainbow'. This mirror is covered with special optical solution that deviate spectrum colors and if properly polarized, might be used on this system (this is probably something from micro or nano-technologies; I am completely illiterate in it).That is why I rather considered putting many small prisms on a big mirror (sheet of thin glass with many cut in prisms in it covered with mirror coating from inside). The idea you describe was my first choice and it seamed to work much better, but I quit it because I found out that light and heat are very friends; not only infra-red rays produce heat, but also all others. Let's look what the Wiki says:

" Infrared light from the Sun only accounts for 49%[11] of the heating of the Earth, with the rest being caused by visible light that is absorbed then re-radiated at longer wavelengths." (Wikipedia, http://en.wikipedia.org/wiki/Infrared).

It confused me a little bit, but if you read the sentence above carefully (not like I did), visible light will produce heat only after it is "re-radiated at longer waves." So, before it is "re-radiated", it might give us some electricity exhausting all of its energy on PV?

Yes, I think you right!

Thank you very much!

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#17
In reply to #8

Re: Rainbow on Photo Voltaic.

03/11/2011 10:32 AM

Dichroic optics, such as the thin film anti-reflection coating on a camera lens, can be "tuned" to pass certain wavelength bands, while reflecting others. One thing you should look at before you dive way off the deep end on the optics, though is the economics of the overall device per kWH produced. Adding a whole wide array of various types of PV may only serve to drive up cost without delivering any extra punch. Consider using a silicon type with the lowest heat coefficient for loss of output that simultaneously has the widest response to the spectrum that will be incident, and you will come up a winner.

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#9

Re: Rainbow on Photo Voltaic.

03/10/2011 8:38 AM

I like your project. Concentrators are being used more and more in solar. Your prism thought is already being used. A number of start up and pre-start up companies are trying this approach. On of the main advantages of splitting the light is you don't need a solar tracker. A number of companies are doing this with film technology to increase the output of traditional panels. You're probably going to have heat issues with your concentrator. Be careful or you might fry your cell during testing until you get the cooling right.

You might want to check these guys out. http://www.prismsolar.com/ Good luck on your project!

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#10

Re: Rainbow on Photo Voltaic.

03/10/2011 1:38 PM

You would almost have to use Automobile hoses that have already cleared for hot oil.

There would be gasket issues.Why use oil when we are at a time when oil is

getting hard to come by.It might be wiser to use some waste product that is similar

to it and more affordable. The questions you need answered are easy to locate in

Wikipedia.com under any word you have used.Soliel Power Plants have built a similar

type of energy producing plant in the CA. Desert using hot steam (water)in copper

tubing and large mirror panels that get turned manually by the plant operator.ds

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#11

Re: Rainbow on Photo Voltaic.

03/10/2011 4:52 PM

How about combining a hot water system with the PV. Tubes behind the PV panel soak up heat from the panel, and keep its temperature down, hopefully improving performance.

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#12

Re: Rainbow on Photo Voltaic.

03/10/2011 4:55 PM

This is being said without trying to discourage you. Most in the solar-thermal field use antireflective coating on the tube to couple the energy to the absorbing medium. I totally get the idea of splitting the incident radiation, and allowing the un-reflected light to reach the absorbing media. There is a problem in concentrated PV that when the PV material heats up, efficiency is majorly lost. You could see some improvement by efficiently de-coupling the infrared (still a major component of incident radiation), from the visible and ultraviolet. I am not an expert on which materials to use for UV, and which for visible, but if you used a dichroic mirror as mirror 2, where the mirror was set up to have high reflectivity below 700nm, and high transmissivity above that wavelength, I think you would have something indeed. Good luck. Perhaps just use "run of the mill" PV material below the prism, or no prism at all, rather a lens to spread the light back to the size of the PV, so you don't "cook" it. (For example a concave cylindrical lens, but you have to choose material carefully to not cut-off the UV.)

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#15

Re: Rainbow on Photo Voltaic.

03/11/2011 8:31 AM

You are expressing creative ideas. In a large field like solar power, with many thousands of people working in it, you can expect to find that most of the ideas you create have already been looked at by others. This is normal and should not discourage you. My comments are about how you analyze your ideas. You have created an interesting idea set. Your intention is "improving efficiency of current solar-power systems." It sounds to me that you are intending to "create new solar power system(s) of higher efficiency than current systems." This may seem to be quibbling over minor details, but it is very important to identify exactly what is the goal of your work. This is because I am suggesting that you need to quantify the elements of your design. That is, you should have at least an estimate of how much the efficiency changes as a result of what you do, and where the effective changes occur. As an example, you collect heat from the mirrored tube because the "steel mirror-like bumper on my van" gets very hot. Well, how hot? Or more importantly, how much energy does it absorb? The reason it gets hot (rises in temperature) is that even though it is reflecting most of the the incident radiation, what the mirror-like finish is best at doing is NOT radiating at the IR frequencies, and since in general more heat is lost from ordinary objects from radiation than from conduction, the internal temperature of the bumper rises to "very hot." Yet just how much energy are you actually going to collect from adding this element of hot oil thermal collector? As has been stated above in another post, the efficiency of present-day solar collectors falls as the temperature rises (the transitions between energy levels in the molecular structure changes), so that you will not get twice the electric power for twice the incident energy. Your "efficiency" seems to be aimed at the amount of energy in the solar radiation, which at present is not in short supply. How about "energy collected per dollar of investment, or of running cost?" Please do not be discouraged by what I say. If you are ready to add this design approach to your work, you will be ahead of the game. Just do not let it squelch the creativity you clearly have within you.

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#16
In reply to #15

Re: Rainbow on Photo Voltaic.

03/11/2011 8:53 AM

Well said.

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#18
In reply to #15

Re: Rainbow on Photo Voltaic.

03/12/2011 12:05 AM

Thanks for your warning and comments! No, you are not discouraging me, and neither does James Steward (#12). I understand that you are here not to discourage someone, but to help, and I greatly appreciate this! I am glad that our discussion is very fruitful (I got new vision on this problem, thanks to all of you) and understand that you worn me to prevent from possible mistakes. Thank you all!

You touched several great questions like efficiency and cost per Watt.

Let me explain what I expect.

First, I am not so naive to expect 2kW of energy from the area that receives only 1kW from the Sun. What I think is that mirror is much cheaper than PV; that is the reason why people try to use concentrated light even on PV. They also build thermal solar-power plants; they do it for a reason: cheaper to build even though the system is much more complicated to build and maintain than PV facility.

The idea to split lights came to me about a year ago when I read somewhere about thermal solar-power plant. I posted it on this forum (http://cr4.globalspec.com/thread/46219#newcomments); my purpose was maybe just like yours: to make our life a little bit better, to breath with fresher air... it's not about money. Solar plants are good especially because they replace fossil-fuel plants; they considered to be 'green' and 'clean'. However, they are not completely 'green' because the area they take is not as green as it used to be before; grass or trees are much greener! In a long run these plants might become another disaster (maybe not like fossil-fuel facilities, but still...) that we will suffer from. That is why efficiency is important for us; I try to find the way how we could utilize all spectrum of the sunlight, not just some part of it. The system with two mirrors was my second choice because it involves very high precision: because the mirrors are faraway one from another, it is easy to reflect the light on the wrong point of the small mirror; if the ray is not pointed exactly to the center-point, it will not come through the prism but will go back to the sky. That was my biggest concern. The reason why I chose this system was because I read that visible light also produces heat (just like you, I concerned about efficiency of hot PV), but thanks to "TopCT", #5 of our discussion, I read it again and think that it is not as big problem as I thought; now I want to turn back to my first choice.

The cost per Watt shell drop down due to using less of PV; I mention much less. Their area will be tens of times smaller than the area of mirror! If IR will be concentrated on a thin heat-collector, the PV-strips will not be much wider, but they will be made of different materials that will work on different colors. One of the problem of PV is that it is 'picky' on spectrum: they might work on some bandwidth while other colors remain useless. With splitting light and using different materials for PV this problem might be gone for a good! The concentrated visible and UV light should not heat PV saving its efficiency.

Yesterday I read Fredski's reply (#9) and went through the Web site he provided. Thank you, Fredski. Something like that HPC Film can be used on my big reflector instead of prism-set. That film deviates light too hard, and we need much smaller deviation; hopefully, it is possible with another similar material.

You know, Fredski, I am glad it is possible to collect light 'from all directions', not only from direct sun; it is just great because these panels can be used on buildings and other structures like above the roads and parking lots. About a year ago I posted another thread on this forum (http://cr4.globalspec.com/thread/46222#newcomments). I think the panels that 'Prism Solar' came up with would be a good solution!

Thank you, gentlemen, one more time for your help and the great discussion we have.

God bless you all!

Andrey.

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#19
In reply to #18

Re: Rainbow on Photo Voltaic.

03/13/2011 7:50 AM

To be more specific in commenting, several aspects of your ideas have already been looked at by others, and found to be not useful to their own work. This includes splitting the frequencies and using customized PV materials for different bandwidths and collecting the energy for PV with mirrors. I would like to emphasize the importance of quantifying - using actual numbers (or ranges of numbers, or symbols to represent numbers, etc) - the characteristics of your concepts. So when you consider a mirror, ask yourself how big a mirror? How accurate does the surface need to be? Can this be purchased from someone else, or do I have to manufacture it myself? How much energy (or power) does the mirror actually absorb? If the secondary mirror is absorbing enough power to justify the cost of a heat collection system, how much energy am I losing in the primary mirror? In general, anything you do to the energy flow will lose you something. So ask yourself, what is it I am losing? The point of using a cost analysis of your ideas is not so you can make lots of money, but so that you can identify whether or not the project is feasible. Good luck. PS - there is much more that can be addressed to the details of your ideas.

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