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Environmentally Friendlier Method of Separating Oil from Tar Sands

03/26/2011 2:01 PM

Paul Painter, professor of polymer science in the Department of Materials Science and Engineering at Penn State, and his group have spent the past 18 months developing a technique that uses ionic liquids (salt in a liquid state) to facilitate separation.

The separation takes place at room temperature without the generation of waste process water. "Essentially, all of the bitumen is recovered in a very clean form, without any contamination from the ionic liquids," Painter explained. Because the bitumen, solvents and sand/clay mixture separate into three distinct phases, each can be removed separately and the solvent can be reused. a-new-process-cleanly-extracts-oil-from-tar-sands-and-fouled-beaches

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#1

Re: Environmentally Friendlier Method of Separating Oil from Tar Sands

03/26/2011 11:38 PM

This principle has been known for quite a while. The more "salty" (ionic) a compound is, the more it will resist miscibility with hydrocarbon liquids (HCs).

the Penn State process completely removes the hydrocarbons, and the cleaned sand can be returned to the beach instead of being sent to landfills.

The word "completely" here is a lie. There will always be some HC residue, whether in ppm or ppb quantities.

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#2

Re: Environmentally Friendlier Method of Separating Oil from Tar Sands

03/27/2011 4:14 AM

Mikerho raises an important conceptual point here. In the world of environmental chemistry, there really is no such thing as zero. (Nor the absolute removal of all contaminants, poisons, etc.) You no doubt have some atoms of plutonium in your body, for instance, just as you have a few water molecules excreted from George Washington's urine. These numbers are quite small, but they can be calculated. Rather than obsessing about some mythical zero, the key is to recognize that below certain small levels, such things don't matter. Unless you are Chicken Little.

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#3

Re: Environmentally Friendlier Method of Separating Oil from Tar Sands

03/27/2011 3:25 PM

This is great news!

Unless there are hidden drawbacks - for example the remaining ionic liquid in the sands after washing? - the cost of this liquid or anything I cannot imagine this will open a new area of oil field use.

Tar sands - yes, but these have not too good hydrocarbon mixtures and a lot of sulfur.

But can there by this process be a better extraction from traditional oilfields that have not a very good extraction rate today?

RHABE

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#4
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Re: Environmentally Friendlier Method of Separating Oil from Tar Sands

03/27/2011 10:35 PM

from the linked material

A small amount of water was used to clean the remaining ionic liquids from the sand, but that water was also recoverable.]/b]

I do see that the middle phase is amber, not clear. I wonder how much is consumed or other wise lost in the process?

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