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PVFD

06/09/2014 2:27 PM

Does anyone have experience exposing PVFD to HF at high pressure and temperature.

We have a machine that came coated with PVFD as a liner, after few months the liner is peeling off.

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#1

Re: PVFD

06/09/2014 3:22 PM
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#2

Re: PVFD

06/09/2014 3:40 PM

Polyvinylidene fluoride is a semi-crystalline polymer that I don't believe is suitable for HF (whatever the F really is) nor high pressure (whatever that pressure might be) and I won't even bother trying to define temperature for you.

Being a polymer, high frequency energy and temperature will age the film rapidly causing the chemical bonds and/or chains to break down prematurely.

Without any specific information about the environment, I think your best off contacting the machine supplier and asking them.

Have some real values at hand before making the call.

PVFD can have piezoelectric properties if processed correctly.

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#3
In reply to #2

Re: PVFD

06/09/2014 4:25 PM

( I knew it was PVDF, I was having him on for not posting it correctly. )

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#4
In reply to #3

Re: PVFD

06/09/2014 5:27 PM
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#14
In reply to #2

Re: PVFD

06/10/2014 8:14 AM

Thank you Lyn,

My problem that I have inherited this machine from previous engineer who did not know much about PVFD. Actually another firm who was overseeing the process of putting the factory together

The outside firm submitted specs to the manufacturer call for 350 F at 100 PSI and they insisted to use PVFD as a liner. One thing to mention that the HF (Hydrofluoric acid) is used after it is heated to 280 F, originally the concentrations of HF used was 70%, we later dropped that to 40%. The liner peeled off when they were running at 70%.

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#17
In reply to #14

Re: PVFD

06/10/2014 8:34 AM

Then refer it back to the equipment manufacturer and get them involved in finding the solution. One hopes it is still under warranty.

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#21
In reply to #14

Re: PVFD

06/10/2014 9:12 AM

"...The outside firm submitted specs to the manufacturer call for 350 F at 100 PSI and they insisted to use PVFD ....."

.

PVDF has a melting point of 350° F, and since it is a thermoplastic and not a thermoset, whenever it reaches that point it will melt again. That is an odd thing for the outside firm to insist upon.

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#23
In reply to #21

Re: PVFD

06/10/2014 9:16 AM

If you only know. Many issues coming up every day

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#5

Re: PVFD

06/09/2014 7:58 PM

Pressure ratings of PVDF (Kynar) pipe and fittings, designed for pipe pressure service.

Kynar is pretty tough stuff. But in the end, whatever service you get from material is whatever service you get.

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#6

Re: PVFD

06/09/2014 10:36 PM

What's "HF"--high frequency, or hydrofluoric acid?

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#7
In reply to #6

Re: PVFD

06/09/2014 11:52 PM

Hydrogen fluoride.

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#8
In reply to #7

Re: PVFD

06/10/2014 12:00 AM

Well, it could have been hot fudge.

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#9

Re: PVFD

06/10/2014 1:49 AM

Alphabet soup!!!!!!! I hate it!!!!!!!

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#10
In reply to #9

Re: PVFD

06/10/2014 2:49 AM

PVDF is completely resistant to alphabet soup, as its pH is near neutral.

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#11

Re: PVFD

06/10/2014 3:06 AM

PVDF...as in Kynar, I actually transpose the letters are PVFD sometimes too, not sure why....anyway, Kynar is one of the preferred materials as far as compatibility with Hydrofluoric acid. It is well suited to high pressures and even very rapid changes in pressure, as PVDF transducers are used to measure pressure in explosive reactions.

.

If the high temperature you mention exceeds around 175° C, that will most likely be the culprit. By 180° C Kynar is completely molten.

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#12

Re: PVFD

06/10/2014 4:15 AM

There are several materials compatibility websites on the internet. Try this:

http://www.coleparmer.com/Chemical-Resistance

<...high pressure and temperature...>

Some numbers on those descriptors would be essential! Please state whether or not the temperature and pressure of the HF were stated to the machine vendor prior to accepting the quotation for its supply and delivery?

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#13

Re: PVFD

06/10/2014 8:13 AM

With PVFD aka Kynar, be careful with your application. If the temperature is too high and the Kynar starts to ignite and burn, a noxious gas is formed and thus can kill/maim if inhaled.

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#15
In reply to #13

Re: PVFD

06/10/2014 8:26 AM

Is that after the HF has done its stuff or before it?

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#16
In reply to #15

Re: PVFD

06/10/2014 8:29 AM

Before

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#18
In reply to #16

Re: PVFD

06/10/2014 8:35 AM

Then it is time to stop using it. About the only things HF won't eat are Kynar and some types of glass.

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#19
In reply to #18

Re: PVFD

06/10/2014 8:45 AM

We just switch to rubber, and it is fine now.

I put this question on to find out more about PVFD (Kynar). We have it everywhere in the factory and I wanted to make sure that we run within the kynar conditions. This machine failed and when I came on we dropped the % of HF and changed the liner.

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#20
In reply to #19

Re: PVFD

06/10/2014 9:02 AM

Bye-bye warranty!

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#22
In reply to #20

Re: PVFD

06/10/2014 9:13 AM

Warranty

It was long gone; this machine was setting idle for over three years because of other issues at the other end of the building.

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