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Boiler Water pH & TDS

02/10/2015 4:51 AM

Dear All,

We have H.P. boiler in operation having capacity 80 T/hr x 65 Bar x 490oC steam. We are using R.O. water for make up and rest condensate from sugar processing. Since last few days boiler water P.H. is 11.2 and TDS 250. These figures are more than normal. We are using blow down but no improvement observed. Please share to resolve the issue.

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#1

Re: BOILER WATER pH & TDS

02/10/2015 5:36 AM

Have you measured the pH and TDS of the RO and sugar processing condensate feeds separately?

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#2

Re: Boiler Water pH & TDS

02/10/2015 10:17 AM

There could be some little amount of NaOH from your condensate from bleaching the sugar. NaOH is a base that's why you have a base solution. Just like JohnDG said, it's preferably have it tested both source for pH and TDS and dilute to proper proportions using

pH(RO)xVolumetric flow (RO)+ pH (sugar condensate) x Volumetric flow (sugar condensate) = Standard pH x (Volume RO+sugar condensate)

You could also do above equation using TDS--just replace pH.

Pls. double check if above equation is correct, but I think it is.

Hope this helps.

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#3
In reply to #2

Re: Boiler Water pH & TDS

02/10/2015 11:04 AM

My Friend,

Thank you and grateful to you.

Regards

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#4

Re: Boiler Water pH & TDS

02/10/2015 12:35 PM

Dear Mr.Muhammad Bilal Bhatti

For the Boiler Pressure of 65 Bar, Boiler Drum Water TDS of 250 is with in limits and it can go up to 500 ppm as Maximum. As regards the pH it should be in the range of 10.8 to 11.0. The Saturation Temp. for water inside the Boler Drum will be 281.9 Deg.C

You have stated the TDS is more than normal. What was the earlier TDS, before you observed the TDS as 250 ppm level. If TDS for the Boiler is low means the blow-down will be higher which means you are throwing out more heat to atmosphere, through the boiler blow-down water, and this lowers the Boiler Efficiency, and result in higher fuel consumption which is a costly affair.

Normally the TDS in the Boiler Feed Water (combination of Condensate returned from sugar plant and make up quantity from RO plant) will be in the range of 3 to 5 ppm, and to reach the limit of 500 ppm, you need 1250 Hrs of Boiler working at full load. You are giving more blow down (when TDS 250) and will be just double the quantity and heat loss will be double.

If TDS in the Boiler increased means the following will be the reason.

1. The RO water quality after treatment will be poor.

2. Some where in the condensate return from sugar plant some raw water is finding its way and getting in to the condensate circuit.

3. The gland cooling water for the condensate pump is sucked in and mix with condensate.

4. There can be an error while drawing the sample from drum and the drum water may flash. The Saturation Temp. at 65 bar will be about 281.9 Deg.C and the sample to be drawn through the cooler so as to approach near ambient temperature say 40 Deg.C. Hence (281.9) - 40 = 241.9 KCal. of heat is to be removed for proper measurement of TDS. If less heat is removed means, the water will flash and it will show higher TDS. Pl. check this immediately.

DHAYANANDHAN.S

P.S. In which Sugar Factory you are working.

DHAYANANDHAN.S

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#8
In reply to #4

Re: Boiler Water pH & TDS

03/17/2015 5:49 AM

Dear Friend,

We have studied your expert opinion practically. The PH range from 10.8 to 11.0 is fine. We are hourly checking condensate from evaporators for TDS and sugar. If TDS in condensate are high it may due to raw water valves leakages but no such case observed since last month.

As you mentioned that normally TDS in feed water are in the range of 3 to 5 ppm then will take 1250 hrs to reach up to 500 ppm. It means that we need not to blow down for about 52 days. Is it advisable?

Below please find boilers water operating data sheet. Please study and comments.

Once again thanks for giving nice tips.

Sr.#

Test Description

Raw Water

RO Water

Condensate

Feed Water

Boiler Water (1)

Boiler Water (2)

1. pH 6.81 5.29 7.05 8.10 11.15 9.50
2. TDS 528 6.00 4.00 6.00 370.00 19.00
3. Conductivity 1061 12.85 8.00 12.92 744.00 39.34
4. Hardness as Ca

2+

n.d. n.d. n.d. n.d. n.d.
5. Hardness as Mg

2+

n.d. n.d. n.d. n.d. n.d.
6. Alkalinity 10.00 125.00 25.00
7. Phosphate (PO

4)

<10 <10 <10

Regards,

M. Bilal

Sr. General Manager

Almoiz Industries Ltd.,

Dera Ismail Khan, PAKISTAN

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#5

Re: Boiler Water pH & TDS

02/10/2015 10:52 PM

Have you checked your instruments for accuracy?

Check each condensate stream to determine source.

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#6

Re: Boiler Water pH & TDS

02/11/2015 11:09 AM

There is really not enough information from your initial post, Mr. Bhatti.

Please give us a bit more history: (1) average boiler TDS for the previous month, (2) average RO TDS and source water TDS (for previous month), processing area condensate (return) TDS average for previous month, and any notes about high values showing up on test records. Also, what portion of steam output is for direct steam heating of the process area, and what portion is used to drive turbine or other machinery to provide motive power in the plant? On a boiler as you describe with low % condensate return the need for blow-down will be more than one with >90% condensate return, and also the boiler TDS can be affected by the ratio of any chemical addition rate (boiler treatments) to blow-down. Do you have a heat recovery system on the boiler blow-down?

Further: what sampling arrangements do you have? Do you have proper sample coolers on these, and what is the cooling water provided to these? What is the calibration interval on your water testing equipment, and are there records of calibrations? Do you have online active instruments that automatically test the boiler water sample? How long since previous calibration? Old style analog sensor technology, or new digital smart sensor technology?

Is the water treatment system comprised of water-softener, RO only, and is the RO a single pass permeate RO? Is there no downstream demineralizing equipment?

What water quality standards have been imposed by the various equipment OEM's that have provided you with equipment using your steam? Is there a silica concentration limit? Iron limit? TDS limit? And so it goes.

Another poster mentions 500 TDS as the upper limit for the class of boiler you have, and I can at least tentatively agree with that, however, certain boiler corrosion issues may become more apparent with this higher TDS level, also there may be boiler carry-over into the steam, through less than unit efficiency of de-misters, silica volatilization into the steam, etc. Solids carryover into the steam can result in superheater damage, and also damage rotating equipment powered by steam.

Does your boiler system incorporate steam attemperation? What is the source of the attemperation water? Is it boiler-feedwater? If so, not being aware of the TDS in that at all times, can lead to a serious problem with contamination of the steam with repect to previous argument requiring protection of downstream equipment.

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#7

Re: Boiler Water pH & TDS

03/13/2015 1:11 AM

Hi Everyone,

I understand your problem. Please check and contact ateindia.com. i am sure it will help you.

Waste Water Treatment , Blow Room

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