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Cracked Glass Jar

11/13/2011 12:43 AM

An expensive colorless glass jar cracked ( 4-5 cm ) while being heated empty( for drying ) in the microwave..is it possible to seal the crack with a trasparent material..?

Thank you

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#1

Re: Cracked glass jar

11/13/2011 12:51 AM

Why not fuse the glass itself back together? Even though I'm no glass blower myself, I have managed to "weld" glass to glass.

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#2
In reply to #1

Re: Cracked glass jar

11/13/2011 12:56 AM

Thanks a lot, I will try this . I am not sure if it will not deform.I was thinking ther might be a glue or chemical special for glass welding. Anyways, thanks again.

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#3
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Re: Cracked glass jar

11/13/2011 1:39 AM

The last time I did this was with an oxyacetylene torch. This is ordinarily too hot, but one can "dial it down" low enough to work. MAPP gas might be a better choice, but look around first; there is probably a lot of good advice on the Web. Good luck!

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#4
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Re: Cracked glass jar

11/13/2011 1:50 AM

Thanks ..

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#5
In reply to #2

Re: Cracked glass jar

11/13/2011 2:26 AM

Anything short of fusing (remelting) the glass will leave you with a crack in your glass, which will continue to propagate unless you stop drill the crack at both ends.

It's always cheaper to just hand dry glassware, oppose to using a micro-wave oven for drying And, I think that if you looked at the small print in the micro-wave oven operation manual, it will say, Do not use the oven without some kind of liquid in a container to absorb the micro-wave energy.

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#6
In reply to #5

Re: Cracked glass jar

11/13/2011 2:44 AM

It was too late when I realized that there is no liquid in the jar..it was fraction of a second.. ! Anyways, thanks a lot for your response..

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#7

Re: Cracked glass jar

11/13/2011 7:08 AM

Forget it. Throw the glass away, now. You will never repair it successfully.

Anyone with enough knowledge and skill to effect a glass repair such as this would never have tried to dry glass in a microwave in the first place.

Maybe try one of those windshield repair kits.

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#8
In reply to #7

Re: Cracked glass jar

11/13/2011 7:19 AM

Thanks.Will try.

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#9

Re: Cracked Glass Jar

11/13/2011 10:07 AM
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#10

Re: Cracked Glass Jar

11/13/2011 11:20 AM

Look into windshield crack repair compounds. The professional ones are cured with UV light.

Don't use your microwave to dry expensive jars. A paper towel, hair dryer or air drying will work better. Glass doesn't like a quick transition from cold to hot.

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#11

Re: Cracked Glass Jar

11/13/2011 11:28 AM

When I suggested windsheild repair, I was half kidding. If this is ornamental glass give the glue a try.

If it is some type of glass that holds a liquid that a person might consume, throw it away.

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#12
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Re: Cracked Glass Jar

11/13/2011 11:45 AM

I only drink from cans or plastic. Even our wine glasses are acrylic. No one gets hurt.

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#13
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Re: Cracked Glass Jar

11/13/2011 11:54 AM

Safety first!

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#14
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Re: Cracked Glass Jar

11/13/2011 12:01 PM

I'm still waiting for the Nerf furniture line to come out. It's a no brainer for the safety conscious family.

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#15
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Re: Cracked Glass Jar

11/13/2011 1:00 PM

Wouldn't last around here. The dog would just eat it.

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#34
In reply to #13

Re: Cracked Glass Jar

11/14/2011 3:53 AM

Thunder!

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#37
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Re: Cracked Glass Jar

11/14/2011 8:17 AM

You must be kidding!

Plastics, no matter how durable, will leach into liquids. Glass is much safer and your wine will taste better.

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#39
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Re: Cracked Glass Jar

11/14/2011 8:41 AM

I know it sounds wrong, but trust me..................glass is not safer around here.

Plastic bounces.

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#54
In reply to #39

Re: Cracked Glass Jar

11/14/2011 11:00 PM

Besides, it takes ages for PCB to leach out of polycarbonate Well ages compared to the beverage 'evaporation rate'.

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#58
In reply to #37

Re: Cracked Glass Jar

11/17/2011 4:46 AM

There is probably a time factor involved in plastics leaching into liquids...

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#16

Re: Cracked Glass Jar

11/13/2011 3:01 PM

What bothers me is that this is an expensive colorless glass jar. This glass is expensive for some reason and you broke it. Any repair will change this piece of glass from what it's supposed to be. If this is a piece of Steuben glass, well you better order a replacement quickly before they're gone. If this is a piece of Lenox crystal, somebody will be able to see this repair. If this glass jar is some special piece of chemical glass ware well even if you're able to fuse this glass there can be stresses in the glass that might make it dangerous for somebody else to use.

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#17
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Re: Cracked Glass Jar

11/13/2011 7:36 PM

Ball Mason jars have become collector items and can sell for hundreds on ebay...Here's a link to one bidding is currently at $250.00 with nearly 3 hrs to go...

http://www.ebay.com/itm/320789213859

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#18
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Re: Cracked Glass Jar

11/13/2011 8:22 PM

I knew that there would be some combination to explain why a glass jar could be expensive that I did not propose. Your proposal though is still just speculation about why the OP's jar is expensive. None the less, the high value of your proposed particular antique Ball Mason jar on e-bay is that this jar has not been repaired but has survived to this era unscathed.

While I sympathize and empathize with the OP about trying to repair the result of misplaced good intentions, there are times that it is better to just accept the consequences. How many times have we seen in politics and other other faux pas that the cover up was worse than the crime.

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#20
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Re: Cracked Glass Jar

11/13/2011 9:17 PM

Well, just supposin, that this guy was cleanin up a jar that his kid had got hold of, and used for holding his pet frog, and that this jar was his wifes prized possession and he just didn't have the heart to tell her...er sumthin? anyway, who cares why people do things...

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#22
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Re: Cracked Glass Jar

11/13/2011 10:31 PM

Well just supposin that I took something from you that was considered valuable only because it was one of the few left that was unbroken and I broke it. I didn't break it to be mean, I broke it from being stupid. Without telling you I try to fix it but I make it worse. Would you be mad at me? What if my attempt to fix it fools you but not an appraiser when you try to sell it. Would you be mad at me?

Would you lend me your car?

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#59
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Re: Cracked Glass Jar

11/18/2011 7:38 PM

My Mustang? No chance

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#19
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Re: Cracked Glass Jar

11/13/2011 8:28 PM

Iron clad proof that there is still a sucker born every minute.

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#21
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Re: Cracked Glass Jar

11/13/2011 9:19 PM

You wouldn't be saying that if you had a cellar full, at least not out loud....

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#60
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Re: Cracked Glass Jar

11/22/2011 8:39 AM

I'd say to take a different approach. Rather than throw it away just because it has one crack, I'd paint a big red arrow on it pointing right at the crack. I'd then double my asking price and claim it had historical value.

{ It worked for the Liberty bell }

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#61
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Re: Cracked Glass Jar

11/22/2011 8:54 AM

Just try painting the crack on your....posterior, and selling that as a historical piece.

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#62
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Re: Cracked Glass Jar

11/22/2011 1:02 PM
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#23

Re: Cracked Glass Jar

11/13/2011 10:43 PM

A Broken Glass Is Like Broken Heart. It's Better To Leave It Alone...

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#24

Re: Cracked Glass Jar

11/13/2011 10:43 PM

Expensive glass, just isn't what it's cracked up to be! Sorry for the pun, I couldn't resist it

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#25

Re: Cracked Glass Jar

11/13/2011 11:38 PM

You could always buy a windshield glass repair kit and spread the solution into the crack.

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#26
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Re: Cracked Glass Jar

11/13/2011 11:41 PM

You must be caught in a time warp.

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#27
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Re: Cracked Glass Jar

11/13/2011 11:49 PM

sjw40364, you might want to look at posts (replies) 7,10 and 11, regarding use of a windshield glass repair kits, which the crack still has to be stopped drilled.

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#28
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Re: Cracked Glass Jar

11/14/2011 12:26 AM

I have repaired glass without drilling holes, that is the optimal solution for best results for strength to make sure the crack gets completely filled. I will say it is messy and time consuming without pre-drilling, but warming the solution first will help you to force it into the crack. Of course if it is a hairline fracture it will most likely only help cosmetically and will more than likely still remain partly visible. I would advise trying it on something else first to practice your technique.

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#29
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Re: Cracked Glass Jar

11/14/2011 12:41 AM

You must be "deaf" too. I can't say that you are "dumb" because I'm not able to hear you speak, if you can. Not that you'd have anything of interest to say. We really aren't repairing windshield glass here.

I'd stick to pointlessly arguing about things which we could agree might not have clear cut answers. Like the eastbound speed of light.

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#30
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Re: Cracked Glass Jar

11/14/2011 1:03 AM

Thanks for your valuable responses.

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#31
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Re: Cracked Glass Jar

11/14/2011 1:20 AM

I give up too! But, Please, Please, do tell me, what the speed is for east bound light? Is it something like, −186,000 mi/s LOL

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#32

Re: Cracked Glass Jar

11/14/2011 1:37 AM

Hi Nabil, maybe as a last accord, here is something that just popped up in my mind: I don't know what a "windshield" repair kit is, never needed one. But I know there is a liquid called "glass water". Sorry, I don't know any sci nomenclature, and if you do find out what is it, take care how you apply it. There may be some leftover that sticks to the glass surface and may look "warped". But still, it is transparent. Again, good luck.

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#38
In reply to #32

Re: Cracked Glass Jar

11/14/2011 8:31 AM

What you are thinking of is not "glass water" but "water glass"! It is a solution of sodium metasilicate Na2SiO4 and has been used in glass repair. Said repair is not structurally sound, and won't endure even nominal use.

Anyway, there is your tidbit of info for the day!

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#33

Re: Cracked Glass Jar

11/14/2011 3:32 AM

Glassy water is sodium-silicate or potassium silicate and on drying needs contact to the carbon-dioxide of the atmosphere to yield soluble carbonate plus polymerised (but still soluble) silicic-acid.

This silicic-acid can be converted to silica-glass on heating to 1200°C and above but is not good for repair of glass. The temperature-coefficient of expansion is too different, so it will crack again.

This full process is much better done with TEOS or tetra-etoxi-silane as used in silicon processing for semiconductors or a similar formulation used in precision casting of high melting-point steels. These materials split off alcohol to yield silicic-acid

Repair by professionals is done most often as follows:

first preheat to near the softening temperature in an oven,

then get a torch - best if hydrogen - oxygen, set to burn at low temperature by hydrogen excess,

heat the region around the end of the crack in a half-circle - this will compress the tip of the crack and prevent elongation,

this heating will start to fuse the crack as temperature is above "melting" ,

if the crack is near disappearing you have to heat both ends with torch else the nonheated end will start to grow,

this procedure should by tried on ordinary glass to get used to it.

If you use bottles (beer or wine) for training these skills, these bottles need an annealing of internal stress - else any crack will grow - give it a trial. This annealing is done by elevated temperature below melting and subsequent slow cooling!

There is an old patent from IBM that traces of caustic sodium or potassium (NaOH, KOH) ca be used to lower the melting temperature of the crack only. I never tried this. If you like to try this: make a 20% or so solution (be careful - highly dangerous for eyes, skin and clothing), attach the parts of the broken glass with iron wire to each other so that the crack is nearly invisible. Let suck in a droplet of the solution so that the crack fills with this solution and let dry slowly - may take weeks if the crack is very tight.

Then put to an oven and the region of the crack will melt first as the alkali will lower the melting point there.

I have a totally broken vase from Gallée the famous French art-nouveau glass manufacturer that awaits repair since years. But as this is double layered I hesitate to try.

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#40
In reply to #33

Re: Cracked Glass Jar

11/14/2011 8:51 AM

Every thing which you are saying is correct except following 1. One need to conditions glass Jar before one can attempt to fix the crack. 2. When crack develop we are creating two new surface and to seal we are going to eliminate one surface and this needs surface to be cleaner 3. As we heat crack area at some place we will go to melting temperature and other just above glass transition temperature and when cooling starts we will have more cracks than we started with 4. Adding liquid glass ( which is 75% SiO2 and 25% Na2O) is good to fix concret since that has calcium aluminum and that reacts in presence of carbon dioxide 5. Needs to look for polymer which will have same refractive index and you can seal at temperature below glass transition temperature of the jar glass materials

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#42
In reply to #40

Re: Cracked Glass Jar

11/14/2011 10:36 AM

Thanks a lot.

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#45
In reply to #40

Re: Cracked Glass Jar

11/14/2011 11:44 AM

I do not agree:

"Every thing which you are saying is correct except following 1. One need to conditions glass Jar before one can attempt to fix the crack"

Insensitive glasses as Pyrex or Quartz-glass do not require preheating and oven cooling to prevent cracks, but sensitive glasses do need this: as uniform cooling as possible!

2. When crack develop we are creating two new surface and to seal we are going to eliminate one surface and this needs surface to be cleaner:

Cleaner than at cracking?? Nobody did talk about allowed dirt, clean as perfect as possible - a problem, I know.

3. As we heat crack area at some place we will go to melting temperature and other just above glass transition temperature and when cooling starts we will have more cracks than we started with...

No, do it right and you will have success. Go to a artisan glass-maker and try to learn. Go to a museum restoration facility where they put together ancient broken glasses and make facsimile of these - they know how to.!

Try yourself - you will have some success. To learn artistic know-how is not an easy job.

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#46
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Re: Cracked Glass Jar

11/14/2011 11:55 AM

I agree with comments #2, #3 and most of #1. Even Pyrex and Quartz-glass need to be throughly heated in areas surrounding a repair so that the temperature gradient is as gradual as practical. Also following heating, all glass should be annealed to reduce internal stresses, otherwise the object will be more fragile than necessary.

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#49
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Re: Cracked Glass Jar

11/14/2011 3:46 PM

After Ph.D. in glass Engineering and working more than 30 years in this field let me try to make an attempt to clear few things 1. Quartz has close to zero expansion so one can heat and cool it down rapidly 2. Pyrex is lithium borosilicate glass with alumina ( alumina increases thermal shock resistance of the glass) is tailored to have zero expansion so one can take the glass from stove to freezer 3. Most of the jar glass is based on sodium- calcium aluminum borosilicate. This glass is blow able type and is low temperature glass with expansion in the range of 5 to 8 part per million. 4. With this high expansion in nature will not be able to thermal shock '5. Most of these type glass has glass transition temperature of 475 to 550 oC 6. Working temperature of these glasses starts around 1000+/-100 to 200oC At this temperature if hand work will create cracks during work and this is the reasons I will not recommend to heat heal the crack

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#50
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Re: Cracked Glass Jar

11/14/2011 4:20 PM

I'm glad to hear that at least you have an above average understanding of the different properties of what most laymen will call "glass". As you point out, there are many different clear silicates out there with widely different thermal mechanic properties that one could make a large jar out of. My point here is that despite our OP coming back several times to thank people (a very polite action that I do appreciate) we still have no idea at all what type of jar this is or why it is considered to be expensive.

For all we know, this could be a large jar of Roman glass. If this is a piece of Roman glass then I say that regardless of the skill of any technician, any attempt to repair this will dramatically diminish the value of the jar. Maybe this glass jar is a pressed glass trophy that can be repaired so that the internal stresses imbalanced by this crack can be properly stabilized. I could go on but I think I've made my point.

My barely trained (I did some of my own small glass blowing many years back) gut feeling is that any amateur repair will be more costly than replacing this jar, one way or another. Even a professional repair might be more expensive than replacement. But without knowing what type of "glass" this jar is made of, all answers are just wild guesses.

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#51
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Re: Cracked Glass Jar

11/14/2011 6:33 PM

I am not sure when this was purchased. If this is old and from Roman it may be made of crystal glass if it is high end product. Crystal glass has very good reflection properties and are generally a high lead containing silicate glass which was very common in old time and still from East Europe area we get high lead crystal wine glass and glass jar. If it is then I will recommend to put in dumpster and by one which is lead free which will be good for all known reasons

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#53
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Re: Cracked Glass Jar

11/14/2011 6:49 PM

I guess I should clarify what I mean by Roman glass. I'm talking about some glass that has been around for a little while. I'll admit that this glass cannot be purchased new.

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#55
In reply to #51

Re: Cracked Glass Jar

11/14/2011 11:04 PM

Does the lead leach out? Or are you concerned about it's use in general?

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#56
In reply to #55

Re: Cracked Glass Jar

11/15/2011 10:05 AM

Under normal use answer is NO Under abuse conditions like leaving acid food let dry then may do that in part per million level (this is guess) If you have acid like hydrochloric acid then a lot

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#57
In reply to #56

Re: Cracked Glass Jar

11/15/2011 2:07 PM

Fortuitous then, that Portuguese vin ordinaire is seldom served in crystal

(and Thanks, very interesting)

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#35

Re: Cracked Glass Jar

11/14/2011 6:43 AM

If you don't want to play chemist by taking the glass back to its molten state, the best bonding material for glass is a one part, clear silicone. It is a product of glass and sand. Moisten the glass before applying, lay a very thin, small bead down, let it dry, cut away the excess and you will get an extremely strong bond. Will it ever look perfect... No Way! But at least your crack will be fixed.

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#47
In reply to #35

Re: Cracked Glass Jar

11/14/2011 3:06 PM

Thanks a lot.

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#48
In reply to #35

Re: Cracked Glass Jar

11/14/2011 3:09 PM

Thanks a lot.

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#36

Re: Cracked Glass Jar

11/14/2011 8:14 AM

You can try Canada Balsam . This is used in Physics optics laboratory to join glass prisms.

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#41

Re: Cracked Glass Jar

11/14/2011 9:56 AM

My guess is that any windshield repair kit no matter how well they seal the crack will still be visible due to their being formulated to a refractive index that matches new windshields.

I would recommend you contact a speciality glassware supplier like ACE Glass Inc. or a scientific supply house like VWR (www.vwrsp.com) or Fisher Scientific (www.fishersci.com) and inquire about having them repair the glass.

We have had several pieces of very expensive glassware repaired at a fraction of the cost of new and in most cases the repair was not noticeable.

Good Luck.

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#43
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Re: Cracked Glass Jar

11/14/2011 10:37 AM

Thanks indeed.

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#44

Re: Cracked Glass Jar

11/14/2011 11:25 AM

Lynn-Door industries sells lovely miniature bumper stickers in a wide variety of subjects. Contact them directly for their latest catalog. There is sure to be one to please. Good luck.

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#52

Re: Cracked Glass Jar

11/14/2011 6:36 PM

Find a local museum and ask them where you can get it restored properly, Don't try drying things in a microwave, dry it in the air.

regards

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