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Combustion power of Hydrogen versus gasoline

05/14/2009 10:12 PM

Fellow scientists. I have tried to get a real answer to this for quite sometime from some very well educated people and have yet to get a straight answer. Here is the issue. A cubic foot of hydrogen yields 270 BTU's. A cubic foot of Natural gas yields 1000 BTU's. If you are running a generator on natural gas I am told you need almost 4x hydrogen to run the engine. Others say no way. Hydrogen delivers more combustion power at the cylinder. Thermodynamics say 4x is closer to the truth. Now take Gasoline engines. How much hydrogen will it take to replace gasoline in an engine that requires 740,000 btu's/hour of natural gas if you sustitute a mix of hydrogen and air. So, How much hydrogen? This engine is an 8 cylinder 3.0L It would be 740 cubic feet of natural gas according to the engineers who manufacture the engine. They had no clue about hydrogen. Please help. It is driving me nuts.

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#1

Re: Combustion power of Hydrogen versus gasoline

05/14/2009 10:18 PM

I do not have my figures in hand, but my original studies showed the fuel value of hydrogen vs gasoline to be as follows: it would take 23 tanker trucks of hydrogen to give you the same miles as a single tanker truck of gasoline.

The engineers and you are frustrated because you are talking cubic feet (volume) and what you really ought to be using is mass.

Sorry i can't give you more info, but my files are "uhh-lost" as my wife is helping me sort my office which as just accumulated for past 10.3 years...

I think that uhh, Blink, had some informative posts on this subject. need to search cr 4

milo

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#2

Re: Combustion power of Hydrogen versus gasoline

05/14/2009 10:26 PM

Try this:

http://cr4.globalspec.com/blogentry/2338

Also anything you can find on the subject by blink. You can take his posts to the bank.

milo

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#3
In reply to #2

Re: Combustion power of Hydrogen versus gasoline

05/14/2009 10:40 PM

Thank you. I realize the energy density of hydrogen is very low compared to gasoline. .24 mj/l versus .02 mj/l. The issue is explosive power. It eludes me. As an engineer and a student and believer in the laws of thermodynamics, I still believe there is more to Hydrogen than we understand. Just adding it to fuel as an additive does such marvelous things such as helping it completly combust the gas or diesel and eliminating emissions is a great start for our environment. Now let us add more and dial back the fossil fuel and replace some with hydrogen for a new begining. Last week, Energy sec. Steven Chu killed all research funding for hydrogen cars. WOW!

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#4
In reply to #3

Re: Combustion power of Hydrogen versus gasoline

05/14/2009 11:05 PM

He did the math.

I'm yet to see the marvelous things that are claimed.

Claims yes. performance data- no.

I've visited Canadian fuel cell research center. This is NOT going to be the answer. for cars.

milo

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#5

Re: Combustion power of Hydrogen versus gasoline

05/14/2009 11:38 PM

Have a look at the following site, it offers a wide range of technical explanations including Hydrogen (both contained and on-demand).

http://www.tinaja.com/h2gas01.asp

Don knows his stuff.

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#6

Re: Combustion power of Hydrogen versus gasoline

05/15/2009 3:51 AM

The first thing to do is to convert everything to energy-per-unit-mass units. One cannot compare a gallon of gasoline to a cubic metre of hydrogen, because a cubic metre of hydrogen's mass will vary with the storage pressure. For that matter, the constituents of gasoline vary, too, with blend.

Think of hydrogen as an energy carrier, rather like electricity, than an energy source.

Consider various methods of storage for road vehicles: liquid gasoline and diesel fuel, compressed hydrogen gas, hig-density battery energy storage, metal hydrides, ultra-high-speed flywheels, etc., and obtain an energy storage value per unit of gross vehicle weight, and also a power-to-weight value for each system. Then one is in a better position to compare 'apples with apples', instead of 'apples with oranges', so to speak.

The biggest thing to overcome is the unspoken constraint to continue to use the internal combustion engine as a power plant for road vehicle propulsion. That assumption may not be valid, perhaps?

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#7

Re: Combustion power of Hydrogen versus gasoline

05/15/2009 5:49 AM

I completely understand and have a good grasp of hydrogen as an enery carrier and agree 100%. It is just that so many colleagues keep pounding the desk claiming that HHO or Hydrogen has magical properties that appear to have been vetted. i am looking for someone with real proof or a deeper understanding. I suppose being limited as a material science engineer having developed a hydrogen reactor to cotrol the reaction of splitting water with aluminum has become a curse. Purdue developed an internally catalyzed alloy that will produce hydrogen when exposed to water alone. fabulous. It will work great with our reactor. The haunting question still lies on the table. I may just have to accept my own beliefs in traditional science for now and be surprised one day.

Thank you for the comments

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#8

Re: Combustion power of Hydrogen versus gasoline

05/15/2009 6:53 AM

You may find this blog by CR4 MaSu interesting.

Regards JD.

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#9

Re: Combustion power of Hydrogen versus gasoline

05/15/2009 7:22 AM

JD, Been through the entire blog by Masu and have a complete understanding of the science and agree. I was looking for something out of the box that probably does not exist. So I will share some recent developments, proprietary as they may be. Using Aluminum which has a greater energy density than coal and IS renewable, we have proven the cost of electricity down to 9 cents per KWH. The system does not require the storage of hydrogen as we all agree that it will find its way out of any available material today. At the very least it will cause hydrogen embrittlement for most steel. If we are ever to put it on the road, fuel cell technology must become more reliable and affordable and storage must become realistic. If we use our reactor, we will need a sterling engine to take advantage of the exothermic recation. No problem for stand alone power generation.

Thanks again. Unless someone has a brilliant revalation, I will stick to what we all know to be true. Did not want appear to be a rookie with the question. Sorry, I should have phrased it better.

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#10

Re: Combustion power of Hydrogen versus gasoline

05/15/2009 8:29 AM

A good question. I have no proof (again, try Blink for a ton of information), but I have experience - lots of it - burning all kinds of fuel. I used to build gas analyzers for industrial applications. Here's the straight scoop as I have seen it many, many times:

Once properly mixed, there is no great difference between fuels due to propagation speed, unless the whole gas stream is at high velocity or is being cooled.

All that counts is BTU content in a properly designed application. In an improperly designed (read inefficient) application, temperature of combustion may become important.

There is no such gas as HHO.

The US DOE has an information agency that publishes many articles on various energy sources.

Any standard combustion engineering book (pick almost anything by John Wiley publishers) covers all this in detail.

ICEs, because of compression ratios, intake/exhaust designs, etc, don't quite follow classic thermodynamic cycles. They are close, however, and the differences have long been documented and confirmed.

Natural gas is usually easier to burn when it has a little hydrogen added. No surprise there; coal miners tell tall tales of outrunning methane explosions - the stuff is slow. If you want to really get into this, you might look at the Markstein number to see how hydrogen affects stability of burning.

Good question. Good luck.

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#11

Re: Combustion power of Hydrogen versus gasoline

05/15/2009 9:40 AM

Fellow engineers,

I am to some extend involved with ICE's and the combustion process. As it was already pointed out, making comparison between fuels we must use the same units, best is J/mass.

The next one to compare is the volume / mass ratio. Gases can be compressed reducing the volume with pressure. But that also costs money and brings difficulties with it.

As far as the "explosive force" is concerned that is not a valid point. Only the heat content of the fuel is of interest. To clarify that a bit more the speed of the flame front determines the time from ignition to completion of combustion. As we have a crankshaft with a generally sinusoidal change in piston position, the earlier all fuel is burned the more mechanical work can be extracted by the crankshaft mechanism. On the other hand, burning too fast results in elevated forces and stress levels of the crank mechanism including that of the crankcase and bolts that must hold it all together.

We speaks of a pressure rise per crank angle which should not exceed a certain value. Diesel engines are build stronger allowing a faster pressure rise.

Hydrogen has a very fast flame speed. Adding it to conventional fuel does increase the rate of combustion and helps therewith in extracting more power to some extend. Using H2 as the sole fuel is however not very good for the engines. In addition, the heating value of the fuel present in the cylinder is lower when compared to gasoline or diesel fuels.

To explain this we must look at it this way. Liquid fuel has a very small volume and can be neglected in volume calculations. Gases however have a relative large volume that must be deducted from the volume of air in the combustion chamber. Remember, we need oxygen for combustion. With less air (oxygen) in the cylinder we can burn less fuel. Making the chamber or rather the cylinder volume bigger is not an even comparison, of course.

If you look at the Mazda Hydrogen fueled Rotary engine you only get at best some 60 % of power from the RX8 engine in comparison to gasoline. It has to do with the lesser oxygen available and the lower heat content per chamber filling. Considering the light weight and hence large volume of hydrogen it is a very poor fuel. Compressing it has only value in its storage. When injected it will expand to the compression pressure.

As far as storage goes there too are problems as we all know. Manufacturing it is also tied to difficulties and as already mentioned in previous posts H2 is to be considered an energy carrier not a fuel that is found in nature as a resource. It is much like electricity as already stated.

To the people who believe that the time of the ICE is over, I would like to suggest that that is not so. I am firmly in the other camp and believe it will live for a long long time to come. Likely until we have found out how flying sources work we will have the ICE.

The problem with the Stirling is to get the temperature difference. The hot side is being feed through the walls from outside. Getting much over 600 C becomes problematic. In the ICE we burn internally. The gas temperature is way above that, over 2000 degrees C, or near 5100 degree F as theoretical flame temperature. A Stirling can never reach that and the claims of 50 - 60 % efficiency are simply false.

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#12

Re: Combustion power of Hydrogen versus gasoline

05/15/2009 11:04 PM

Check this report out for hydrogen engines. It is a fairly well written primer for the hydrogen ICE (Internal Combustion Engine) with some reasonably good explanations.

Hydrogen is limited by volumetric displacement of air and surface ignition tendency. That is why many researchers hit a practical limit of 60% torque relative to gasoline. Direct injection (late cycle) and turbocharging can give you much better results.

http://www.panaceauniversity.org/Hydrogen%20use%20in%20internal%20combustion%20engines.pdf

see figure 3-3.

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#15
In reply to #12

Re: Combustion power of Hydrogen versus gasoline

05/16/2009 10:06 AM

thanks for the reply although the image did not load for some reason. Please send to joe@ w3ig.net if you have the time. It would be greatly appreciated. The report was very helpful!

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#13

Re: Combustion power of Hydrogen versus gasoline

05/16/2009 5:40 AM

I used to believe in Hydrogen - fuel of the future,
but practicalities determine otherwise.

Now, I have more faith in sodium/ceramic batteries and
their development. (link supplied in previous thread)

Apparently they have 20-40kva batteries now, soon to
go into production, and this will revolutionise transport
and home power. Forget H - the futures in batteries.
(supplied from renew-ables of course, wind tidal sun, etc.)

jt.

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#16
In reply to #13

Re: Combustion power of Hydrogen versus gasoline

05/16/2009 10:23 AM

For what it is worth, the only solid element more abundant on the planet than Si is Al It is easily processed into aluminum and had a higher energy density than coal. Using it to split water to make hydrogen is a simple process and can now be used on demand. Not as an electrolysis device producing 2h2 02[what the non-scientist call HHO], but as an on board process or stand alone generation, using an Al alloy. This technology is not years into the future. We possess this technology and hope to release it by 2010 for various applications. cars are last on the list if ever.

Battery technology is still decades away. The best the industry has to offer for cost and reliability is the old stand by lead acid battery. Granted we are making great progress and I applaud and pray for the them.

PEM fuel cell technology is still too fragile and too expensive. Solid oxide fuel cells show the most promise at the moment.

As a new user of this powerful forum, I want to thank all you gurus who have taken the time to read, research and assist. When I post in the future i know I will take greater care to be very specific and respect your time. I am humbled

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#18
In reply to #16

Re: Combustion power of Hydrogen versus gasoline

05/16/2009 4:22 PM

Would you be willing to share with us the process by which Al is used to break the water molecule bond? Showing it as an equation would be very helpful.

Thank You.

Gavilan

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#19
In reply to #18

Re: Combustion power of Hydrogen versus gasoline

05/16/2009 6:19 PM

We are going off topic and should probably start a new thread, but I am still new. So, You Gurus please advise me.

The process to control the reaction is the key and is proprietary, but will entertain investors.

There are several ways to complete the reaction. Here is the basic. Not for amateurs, please do play with this as it is very dangerous if you are working under pressure and do not purge the reactor with an inert gas prior to the introduction of the NAOH and water.

2 Al(s) + 6 NaOH(aq) → 3 H2 (g) + 2 Na3AlO3(aq)

Using 540 grams[~1#] (2 MOLs) of Aluminum you can produce 6 grams (3 MOLs) of hydrogen (H2), which will have 672 liters[~24CuFt] of volume under the atmospheric pressure. You will also consume 2400 grams[[`5#] of NAOH

We have completed many trials with 400 KG and measured volume with an analog meter and measured over 22,000 cubic feet or over 600,000 liters of hydrogen consistently.

This is a fairly large prototype reactor and is an engineered system. Welded by professionals, built out of materials that are not susceptible to hydrogen embrittlement, with a Nitrogen pad for purging the atmosphere before start up, etc. I mention this as I want to discourage shop building this device. Even engineers should be warned. On a small scale, a leak a pressure can cause some very undesireable results.. The technology is perfcetly safe when designed and managed properly. H2 will take off into the atmosphere at 20m/s if you do have a leak. No problem.

There are many other ways to react aluminum with water to produce hydrogen, but the net result is the same 1:1.5 One mole of Al in with water, 1.5 moles of hydrogen out. The only difference is the amount of water you use and the by product.

The example above will yield a beautiful nano refractory that will never dry completely with some other interesting applications. There is an alloy that uses only water to react and produces mostly Al2O3, except it is very expensive and you must first process the Aluminum. The system and reaction I describe uses scrap aluminum and requires no prep what so ever. Just dump it in the hopper and our system will take of the rest.

We also looked at using Silicone metal from SiO2. it shows promise and IS the most abundant and renewable second to Al on the planet. We are still back to H2 as an energy carrier. Siemmens work in Soilid Oxide Fuel cells dove tails nicely into our process as 49% of our reaction is heat which we can use in so many ways. 51% is H2

Now I am Just waiting on MY OBAMA MONEY through Steven CHU and the DOE. This is me holding my breath.............

You can do this as a back yard yard experiment with Aluminum foil, cans and source of lye. If you mix some liquid detergent in the water, you can capture the bubbles and ignite with a bar-b-que lighter DO NOT LET TOO MUCH ACCUMULATE AND DO IT OUTSIDE!. I am alomost sorry I posted it, but it proves the point of how powerful an energy carrier gas from aluminum can be.

Hope this gets you started and answers your questions and then some. If I ever learn how to use this medium to its full extent, I have an enormous amount of data to share on the topic for those who are interested.

Godspeed, Joe

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#21
In reply to #19

Re: Combustion power of Hydrogen versus gasoline

07/04/2019 7:09 AM

H2 is dangerous because it has a very wide range of fuel/air mixtures at which it can ignite.

From memory the range is from 1 or 2% up to around 95%.

Practically no other fuel can ignite over such a wide range.

The disadvantage of H2 is that it is so light that a lot of volume is required to get a decent amount of energy when compared to hydrocarbons.

Many abundant materials will react with water to generate H2, but usually a considerable amount of electricity is needed to make the raw material in the first place.

An electrolytic cell is more efficient, especially if run at high pressure. This also makes storage of the resultant H2 easier as you generate at the pressure at which you want to store.

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#14

Re: Combustion power of Hydrogen versus gasoline

05/16/2009 9:07 AM

Certainly the engine manufacturers have done dynamo tests on this subject, but I dont know where to retrieve the data. or reports.

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#17
In reply to #14

Re: Combustion power of Hydrogen versus gasoline

05/16/2009 3:39 PM

Sources of Hydrogen reports: Search the SAE website under papers. Ford and BMW have published very good material in the last 5 years.

http://www.sae.org/technical/papers/

Search under Ford, BMW, hydrogen ... there are many good papers and summaries. Due to copyright, you can only see the abstract but papers can be purchased for $10 or so.

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#20

Re: Combustion power of Hydrogen versus gasoline

05/10/2019 11:54 PM

...few years later, but might be helpful... a car with 4L engine requires 4L of hydrogen/min to idle... a dry HHO cell (7plates 20"sq stainless brushed steel @ 12VAC/10Amps) makes 1L/min hydrogen...

I've made a mega cell and it does produce that amount...

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